烷基糖苷季铵盐表面活性剂复配性能研究

doi:10.3969/j.issn.1001-1803.2020.03.006

Abstract

Abstract:

The butylglucoside and octylglucoside were compounded with 3-chloro-2-hydroxypropyl dimethyl dodecylamine salt and 3-chloro-2-hydroxypropyl dimethyl hexadecyl salt according to the molar ratio of 1∶1,1∶0.5 and 1∶0.1. The surface tension, critical micelle concentration （cmc）, hydrophile-lipophile balance （HLB）, foam property, detersive performance and emulsifying property of the complex system were also determined. The results show that the performance of octylglucoside hydroxypropyl dimethyl dodecylammonium hydrochloride compounded with anionic surfactant is good. The surface activity and hydrophilicity of butylglucoside hydroxypropyl dimethyl dodecyl ammonium hydrochloride samples are good. When the mass fraction of butylglucoside and octylglucoside was 80%, the foam properties, emulsification properties and stability of butylglucoside hydroxypropyl dimethyl hexadecyl ammonium hydrochloride were all in good condition. The decontamination performance of butylglucoside hydroxypropyl dimethyl hexadecyl ammonium hydrochloride compound system is good for carbon black cloth and protein stain cloth.

Key words: alkyl glycosides, quaternary ammonium salts, compound properties, hydrophilicity, decontamination properties, emulsification properties

CLC Number:

TQ423

Li-ying JIANG. Study on compound properties of alkyl glycoside quaternary ammonium surfactant[J].China Surfactant Detergent & Cosmetics, 2020, 50(3): 171-176.

Figures/Tables 8

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Tab. 2

Tab. 3

References 16

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配制物		二者摩尔比	生成物	生成物编号
丁基葡萄糖苷	3-氯-2羟基丙基二甲基十二烷基铵盐	1∶1 1∶0.5 1∶0.1	丁基葡萄糖苷羟基丙基二甲基十二烷基铵盐酸盐	1 2 3
辛基葡萄糖苷	3-氯-2羟基丙基二甲基十二烷基铵盐	1∶1 1∶0.5 1∶0.1	辛基葡萄糖苷羟基丙基二甲基十二烷基铵盐酸盐	4 5 6
丁基葡萄糖苷	3-氯-2羟基丙基二甲基十六烷基铵盐	1∶1 1∶0.5 1∶0.1	丁基葡萄糖苷羟基丙基二甲基十六烷基铵盐酸盐	7 8 9
辛基葡萄糖苷	3-氯-2羟基丙基二甲基十六烷基铵盐	1∶1 1∶0.5 1∶0.1	辛基葡萄糖苷羟基丙基二甲基十六烷基铵盐酸盐	10 11 12

复配体系	3种污布	w（APG）/%
复配体系	3种污布	0	20	40	60	80	100
丁基葡萄糖苷羟基丙基二甲基十六烷基铵盐酸盐	碳黑污布	5.3	5.5	5.8	6.1	7.4	13.5
	蛋白污布	2.2	2.5	2.6	2.8	2.9	5.2
	皮脂污布	1.3	2.1	1.8	1.5	1.2	4.9
辛基葡萄糖苷羟基丙基二甲基十六烷基铵盐酸盐	碳黑污布	4.2	4.5	5.2	5.7	6.1	12.3
	蛋白污布	1.8	1.9	2.3	2.5	2.6	4.7
	皮脂污布	0.6	1.0	0.7	0.6	0.5	3.9

w（APG）/%	t/min
w（APG）/%	丁基葡萄糖苷羟基丙基二甲基十六烷基铵盐酸盐	辛基葡萄糖苷羟基丙基二甲基十六烷基铵盐酸盐
0	13.9	13.7
10	15.1	13.8
20	16.2	13.0
30	16.1	12.9
40	16.0	12.0
50	15.9	13.2
60	15.7	13.7
70	15.8	14.2
80	16.1	15.9
90	13.2	13.2
100	10.0	10.0

Study on compound properties of alkyl glycoside quaternary ammonium surfactant

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References 16

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