一种酰胺型Gemini表面活性剂的合成及性能

doi:10.3969/j.issn.1001-1803.2020.03.001

Abstract

Abstract:

An amide Gemini surfactant N,N’-bis-dodecyl-2,6-pyridinium dimethylamide propionate sodium（DLP-12） was synthesized from dodecylamine, methyl acrylate, and 2, 6-pyridine-dicarboxylic acid by addition, amidation, and saponification reactions. By single factor experiments, the optimum reaction conditions for this reaction were: n（N-dodecyl-β-alanine-methyl ester）∶n（2, 6-pyridine-dicarboxylic acid）=2.4∶1, reflux reaction at 40 ℃ for 8 hours. Under these conditions, the yield of the final product was 68.14%. The results showed that the critical micelle concentrations of DLP-12 were 9.1×10 ^-5, 9.5×10 ^-5and 9.7×10 ^-5mol/L at 25, 35 and 45 ℃, respectively, and the corresponding surface tension were 33.7, 32.4 and 31.1 mN/m, respectively. The maximum surface excess concentration （Γ_max） decreased with the increase of temperature. The value of the critical packing parameter （CPP） indicated the self-assembly morphology of surfactants in aqueous solution transformed from lamellar structure to rod-like structure. At 25 ℃, the emulsification properties measured with liquid paraffin and n-octane as the oil phase were 277 and 252 s, respectively, and the Roche foam height was 141 mm.

Key words: N, N’-bis-dodecyl-2;, 6-pyridinium dimethylamide propionate sodium, dodecylamine, addition, amidation, 2, 6-pyridine-dicarboxylic acid, Gemini surfactant

CLC Number:

TQ423

Yong-chen CAI,Hua-sheng ZHENG,Hu-jun XU. Synthesis and properties of an amide Gemini surfactant[J].China Surfactant Detergent & Cosmetics, 2020, 50(3): 143-148.

Figures/Tables 9

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References 21

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温度/℃	cmc/ （mol·L^-1）	γ_cmc/ （mN·m^-1）	Γ_max×10¹⁰/ （mol·cm^-2）	A_min/nm²	pc₂₀	CPP	自组装形状
25	9.1×10^-5	33.7	2.561	0.648	4.378	0.648	层状
35	9.5×10^-5	32.4	1.801	0.922	4.447	0.455	棒状
45	9.7×10^-5	31.1	1.745	0.952	4.568	0.441	棒状

表面活性剂	cmc/（mol·L^-1）	γ_cmc/（mN·m^-1）
DLP-12	9.1×10^-5	33.7
CTAB	9.8×10^-4	37.3
SDS	8.0×10^-3	32.0
APPZ-12	8.3×10^-4	32.7

表面活性剂	泡沫高度/mm		乳化性/s
表面活性剂	起始高度	5 min后	液体石蜡	正辛烷
DLP-12	141	138	277	252
CTAB	122	116	159	196
SDS	138	133	226	36
APPZ-12	212	208	223	214

Synthesis and properties of an amide Gemini surfactant

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