非水相溶致液晶形成的研究进展

doi:10.3969/j.issn.1001-1803.2019.12.009

Abstract

Abstract:

With wide applications of lyotropic liquid crystals in the fields of bionics, functional materials, chemical industry, medicine, petroleum industry, daily cosmetics, etc., the research of constructing non-aqueous phase liquid crystals attracts more attention recently. Based on the basic theory of the formation of the lyotropic liquid crystals of surfactant aggregates, the formation, characterization and application of the lyotropic liquid crystals of surfactants in non-aqueous solvents such as straight chain alcohols （glycerin, ethylene glycol, etc.）, organic amines （formamide, N-methylformamide, etc.）, ionic liquids, etc. are reviewed, and the development trend in this field is prospected.

Key words: non-aqueous solvent, surfactant, lyotropic liquid crystals

CLC Number:

TQ423

XI Qi,YAN Yong-li,ZHANG Yang. Progress in the formation of lyotropic liquid crystals in non-aqueous solvent[J].China Surfactant Detergent & Cosmetics, 2019, 49(12): 817-823.

Figures/Tables 7

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Tab. 2

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References 48

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P值	胶束形状
P≤1/3	球状
1/3≤P≤1/2	棒状或椭球状
1/2≤P≤1	层状或囊泡
P≥1	反相聚集体

	直链醇	有机胺化合物	离子液体	对二甲苯	液体石蜡	角鲨烯	角鲨烷	橄榄油
卵磷脂^[20,21]	√	×	×	×	×	×	×	×
十二烷基硫酸钠^[22,23]	√	√	×	×	×	×	×	×
K-皂^[24]	√	×	×	×	×	×	×	×
三乙醇胺油酸酯^[25,26]	√	√	×	√	×	×	×	×
烷基三甲基铵^[27,32]	√	√	√	×	×	×	×	×
N-烷基吡啶鎓氯（溴）化物^[28,29,33]	√	√	√	×	×	×	×	×
BPS-n^[30,31,34]	√	√	√	×	×	×	×	×
Q_n-D ^[36,37]	×	×	×	×	√	√	√	√

中间相	峰值比率
层状相	1∶2∶3∶4
立方胶束（fcc）
立方胶束（bcc）
双连续立方体（Im3m）
双连续立方体（Pn3m）
双连续立方体（Ia3d）
六角相

Progress in the formation of lyotropic liquid crystals in non-aqueous solvent

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