含刚性基团的Gemini表面活性剂的制备及其与SDS复配性能研究

doi:10.3969/j.issn.1001-1803.2019.05.004

Abstract

Abstract:

A Gemini surfactant containing the rigid linking group（G₁₄）was synthesized from phthalic anhydride, epichlorohydrin and N,N-dimethyltetradecylamine. The structure was characterized by electrospray mass spectrometry and ¹H NMR. The surface activity and application properties of the mixtures of G₁₄ and sodium dodecyl sulfate（SDS）were studied. The mixed systems have exhibited a lower critical micelle concentration（cmc）, a stronger emulsifying ability, and better wetting properties than a single component. When n（G₁₄）∶n（SDS）=1∶2, the cmc is 3.19×10 ^-5 mol/L; γ_cmc is 22.3 mN/m; A_min is 0.57 nm ²; pc₂₀ reaches 5.01; Г_max reaches 2.92 μmol/m ²; the cleaning rate of diesel can reach 91.67% at 65 ℃.

Key words: rigid group, Gemini surfactant, compounding, surface activity, application performance

CLC Number:

TQ423.12

ZHANG Wen-zhe,LI Pan,HOU Lin-xi. Preparation of Gemini surfactants containing rigid groups and their properties after mixed with sodium dodecyl sulfate[J].China Surfactant Detergent & Cosmetics, 2019, 49(5): 298-303.

Figures/Tables 9

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References 18

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n（G₁₄）: n（SDS）	H₂O	1:0	3:1	1:1	1:2	1:3	0:1
p₁/g	23.52	22.63	24.48	23.97	26.71	21.29	24.74
p₂/g	24.04	23.11	24.97	24.55	27.19	21.80	25.24
p₃/g	23.98	22.92	24.81	24.32	26.90	21.59	25.14
h/%	11.54	60.42	73.47	81.03	91.67	80.39	40.00

Preparation of Gemini surfactants containing rigid groups and their properties after mixed with sodium dodecyl sulfate

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