一类以对苯二胺为联接基的双子表面活性剂的合成及性能

doi:10.3969/j.issn.1001-1803.2019.05.003

Abstract

Abstract:

A series of novel Gemini surfactants C₁₂, C₁₆, and C₁₈with the hydrophobic groups of different lengths were synthesized with epichlorohydrin, N, N-dimethylalkyl amine and p-phenylenediamine as materials in two steps. The products were characterized by FT-IR and ¹H NMR. The critical micelle concentration（cmc）and the corresponding surface tension（γ_cmc）of the phenylenediamine surfactants in aqueous solution were measured at 25 ℃ by surface tensiometer. The Krafft points and the emulsifying, foaming and antimicrobial properties of the aqueous solutions were also determined. The results show that the cmc of C₁₂, C₁₆ and C₁₈ at 25 ℃ are 3.29×10 ^-3, 2.53×10 ^-4 and 3.14×10 ^-4 mol/L, respectively, and the γ_cmc are 28.24, 31.95 and 35.06 mN/m, respectively. The Krafft points of C₁₂ and C₁₆ are both below 0 ℃, and the Krafft point of C₁₈ is 10 ℃. The foaming properties of C₁₂ are better than those of C₁₆ and C₁₈. The emulsifying properties of C₁₈ are better than those of C₁₂ and C₁₆. C₁₂, C₁₆ and C₁₈ have shown excellent antimicrobial activities.

Key words: Gemini surfactant, surface activity, foaming property, emulsifying property, antimicrobial property

CLC Number:

TQ423

WANG Chen,XU Hu-jun. Synthesis and properties of a series of Gemini surfactants with p-phenylenediamine as a spacer[J].China Surfactant Detergent & Cosmetics, 2019, 49(5): 293-297.

Figures/Tables 3

References 18

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产物	cmc/（mol·L^-1）	γ_cmc/（mN·m^-1）	pc₂₀	10¹⁰Γ_max/（mol·cm^-2）	A_min/nm²
C₁₂	3.29×10^-3	28.24	4.02	1.32	1.25
C₁₆	2.53×10^-4	31.95	4.28	1.44	1.15
C₁₈	3.14×10^-4	35.06	4.12	1.48	1.12

产物	t/min	抑菌率/%
产物	t/min	大肠杆菌	金黄色葡萄球菌	白色念珠菌
C₁₂	2	>99.99	>99.99	>99.99
	5	>99.99	>99.99	>99.99
	10	>99.99	>99.99	>99.99
	20	>99.99	>99.99	>99.99
C₁₆	2	>99.99	>99.99	>99.99
	5	>99.99	>99.99	>99.99
	10	>99.99	>99.99	>99.99
	20	>99.99	>99.99	>99.99
C₁₈	2	0	>99.99	99.89
	5	28.89	>99.99	>99.99
	10	99.78	>99.99	>99.99
	20	>99.99	>99.99	>99.99

Synthesis and properties of a series of Gemini surfactants with p-phenylenediamine as a spacer

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