异构十三醇聚氧乙烯醚系列及其聚氧丙烯醚（3）封端物的构效关系研究

doi:10.3969/j.issn.1001-1803.2019.04.003

China Surfactant Detergent & Cosmetics ›› 2019, Vol. 49 ›› Issue (4): 220-223.doi: 10.3969/j.issn.1001-1803.2019.04.003

• Development and application • Previous Articles Next Articles

Structure-property relationship in the series of iso-tridecanol polyoxyethylene ethers and their derivatives terminated with polyoxypropylene （3） block

HUANG Zhong-rui^1,²,LV Jia-le²,KANG Wen-qian²,CAO Wen-li²,WANG Li-min^1,²(),CHE Fei³

^1. Shanghai Key Laboratory of Functional Materials Chemistry, Shanghai 200237, China
^2. Institute of Fine Chemicals, School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai 200237, China
^3. Shanghai Bronkow Chemical Co., Ltd., Shanghai 201512, China

Received:2018-08-16 Revised:2019-04-03 Online:2019-04-22 Published:2019-04-24
Contact: Li-min WANG E-mail:wanglimin@ecust.edu.cn

Abstract

Abstract:

The structure-property relationship of iso-tridecanol polyoxyethylene ether with different number of ethylene oxide （EO） units was studied, as well as their performance after blocking with 3 units of propylene oxide （3PO）. The surface tension, critical micelle concentration （cmc）, wetting properties, foam properties, emulsifying power and cloud point of iso-tridecanol polyoxyethylene ethers and 3PO-blocked iso-tridecanol polyoxyethylene polyoxypropylene ether were investigated. The results show that the minimum surface tension （γ_cmc）, the cmc, the foam stability and the foaming power, the wetting time and the cloud point of iso-tridecanol polyoxyethylene ether are increased with the increase of the EO number. It is also found that when PO is blocked, its surface tension is increased; the cmc, foam stability, foaming and emulsifying ability and cloud point are decreased; when the EO number is greater than 9, the wetting force is increased. In summary, the structure of polyethers affects their properties.

Key words: iso-tridecanol polyoxyethylene ether, iso-tridecanol polyoxyethylene polyoxypropylene ether, ethylene oxide, propylene oxide, structure-property relationship

CLC Number:

TQ423.2

HUANG Zhong-rui,LV Jia-le,KANG Wen-qian,CAO Wen-li,WANG Li-min,CHE Fei. Structure-property relationship in the series of iso-tridecanol polyoxyethylene ethers and their derivatives terminated with polyoxypropylene （3） block[J].China Surfactant Detergent & Cosmetics, 2019, 49(4): 220-223.

Figures/Tables 6

Fig.1

Fig.2

Fig.3

Fig.4

Tab.1

Fig.5

References 7

[1]	Wu Huaping, Sun Yongqiang, Kang Baoan . Relationship between the structure and performance of non-ionic surfactants[J]. Detergent & Cosmetics, 2012,35(6) : 17-21.
[2]	Zhao Xuehua, Huang Zhongrui, Kang Wenqian , et al. Study on the surface performance of cardanol polyoxyethylene ether[J]. China Surfactant Detergent & Cosmetics, 2017,47(9) : 492-496.
[3]	Lv Haiyan . Study on synjournal of hterogeneous carbon-13 fatty alcohol ether[J]. Technology & Economics in Petrochemicals, 2016,32(3) : 23-27.
[4]	Gao Hongjun, Chen Shiming, Jin Yifeng , et al. Synthetic process of diphenylethene phenol polyoxyethylene ether (10)[J]. Chemical Industry and Engineering Progress, 2017,36(12) : 4635-4640.
[5]	Azum N, Rub M A, Asiri A M , et al. Micellar and interfacial properties of amphiphilic drug-non-ionic surfactants mixed systems surface tension, fluorescence and UV-vis studies[J]. Colloids and Surfaces A, 2017,522:183-192. doi: 10.1016/j.colsurfa.2017.02.093
[6]	Bournival G, Du Z, Atan S , et al. Foaming and gas dispersion properties of non-ionic surfactants in the presence of an inorganic electrolyte[J]. Chemical Engineering Science, 2014,116:536-546. doi: 10.1016/j.ces.2014.05.011
[7]	Zheng Guo, Xiao Changfa . Correlation between structure and properties of polyether nonionic surfactants[J]. Journal of Tianjin Polytechnic University, 2007,26(4) : 19-24.

样品	乳化时间/min
1307	17.4
1308	18.8
1309	16.0
1310	16.5
1311	17.0
1373	15.4
1383	15.9
1393	16.3
13103	13.8
13113	14.6

Structure-property relationship in the series of iso-tridecanol polyoxyethylene ethers and their derivatives terminated with polyoxypropylene （3） block

RichHTML

PDF (PC)

Like

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 6

References 7

Related Articles 3

Metrics

Comments

Recommended 10

[1]	WANG Xin-gang,YANG Xiao-yi,SUN Yong-qiang,GUO Chao-hua,LI Ping,LI Jian-bo. Study on the properties of the mixtures of sodium fatty alcohol ether sulfate with narrow ethylene oxide distribution and tetradecyltrimethylammonium bromide [J]. China Surfactant Detergent & Cosmetics, 2019, 49(8): 485-491.
[2]	TAN Fu-neng. Preparation of network gel of polyethylene oxide/sodium alginate/hydroxypropyl-decyl chitosan and its behavior for in vitro release of panax notoginseng saponins [J]. China Surfactant Detergent & Cosmetics, 2018, 48(4): 205-209.
[3]	WANG Qi-hui,LI Ming,ZHAN Xue-fang. Determination of propylene oxide in cleaning cosmetics by HS-GC/MS [J]. China Surfactant Detergent & Cosmetics, 2016, 46(1): 58-60.