12-3(OH)-12型表面活性剂ADAC的合成及性能研究

doi:10.13218/j.cnki.csdc.2016.11.003

Abstract

Abstract: A kind of hydroxyl propyl Gemini ammonium chloride cationic surfactant,1,3-bis(alkyldimethylammonium chloride) isopropanol (ADAC) was synthesized with dodecyl dimethyl amine (12DMA) as main starting material under acidic condition.The purity of ADAC in the product reaches 98.63%,which was determinated by methylene blue back titration method,and its melting point is 70.7~71.2 ℃.The chemical structure of the product was characterized by means of FT-IR and ¹H NMR.Based on single factor experiments,the optimum conditions were obtained using response surface methodology as:reaction temperature,91 ℃;reaction time,11 h;solvent,isopropanol;n(12DMA)∶n(hydrochloric acid)=2.03∶1;stirrer rotation speed,250 r/min.Under the aforesaid conditions,the reaction yield of ADAC achieves 93.37%.Surface performance of the target product at 15 ℃ was measured as:cmc,4.5×10^-5 mol/L;γ_cmc,27.07 mN/m;effectiveness (π_cmc),45.99 mN/m;efficiency (pc₂₀),5.301.

Key words: Gemini quaternary ammonium salts, synthesis, response surface methodology, optimization, surface performance

CLC Number:

TQ423.12

GUO Rui,LI Huan-le,LIU Ai-yu,YANG Jiang-yue,CHENG Min. Synthesis and performance of 12-3(OH)-12 type surfactant ADAC[J].China Surfactant Detergent & Cosmetics, 2016, 46(11): 622-627.

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Synthesis and performance of 12-3(OH)-12 type surfactant ADAC

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