W-SN交联剂的合成及其交联性能研究

doi:10.3969/j.issn.2097-2806.2025.03.002

Abstract

Abstract:

Fracturing is an important stimulation means for low-permeability oil reservoirs to increase their productivity. The normal operation of hydraulic fracturing largely depends on whether the fracturing fluid has excellent heat and shear resistance which in turn depends on the crosslinking agent. In this work, melamine, sodium tetraborate, and zirconium oxychloride were used as raw materials to synthesize a new W-SN crosslinking agent through “one-step method”. Under laboratory conditions, the performance of the fracturing fluid used with this crosslinking agent was evaluated. By study of the preparation process of W-SN crosslinking agent, the optimized synthesis conditions were obtained as follows: 5wt% zirconium oxychloride, 1wt% melamine, 2.5wt% sodium tetraborate, pH of 0.5, temperature of 90 ℃, and reaction time of 4 hours. The optimized conditions for gelation with partially hydrolyzed polyacrylamide （HPAM） were as follows: crosslinking time, 25 minutes; mass ratio of HPAM to W-SN, 100∶2.5. Both W-SN crosslinker and the HPAM gel show improved salt tolerance and thermal stability, satisfying the practical requirements of hydraulic fracturing operation.

Key words: fracturing fluid, organic boron zirconium crosslinking agent, thermal stability and shear resistance, synthesis

CLC Number:

TQ423

Haibing Cheng, Yong Zhang, Lei Sun, Weijia Li, Zhi Chen, Congming Tang, Li Chang. Synthesis and crosslinking properties of W-SN crosslinking agent[J].China Surfactant Detergent & Cosmetics, 2025, 55(3): 279-285.

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References 23

[1]	Meng Chun, Liu Chengjun, Zhang Ye, et al. Experimental study on damage and control methods of fracturing fluid retention to tight shale matrix[J]. Chemistry and Technology of Fuels and Oils, 2024, 59 (6): 1184-1194.
[2]	Liu Tianyu, Ye Zhongbin, Liu Dong. Preparation and performance evaluation of P (St-AM) microencapsulated gel-breaking agents with core-shell structure[J]. Chemistry and Technology of Fuels and Oils, 2024, 60 (2): 309-314.
[3]	Yang Xiaojiang, Chen An, Mao Jincheng, et al. Synthetic polymer fracturing fluid weighted by sodium formate enables fracture stimulations in Ultra-High pressure and High-Temperature reservoir[J]. Fuel, 2023, 353: 129170.
[4]	王贤君, 张明慧. 双链表面活性剂压裂液研究及应用[J]. 大庆石油地质与开发, 2015, 34 (5): 77-80.
[5]	Shi Shenglong, Sun Jinsheng, Mu Shanbo, et al. Effect of chemical composition of metal-organic crosslinker on the properties of fracturing fluid in high-temperature reservoir[J]. Molecules (Basel, Switzerland), 2024, 29 (12): 2798.
[6]	Wang Xiqiu, Wang Fang, Zhang Yu, et al. Novel hydrophobic associative copolymers for natural gas hydrate fracturing fluids[J]. Journal of Molecular Liquids, 2024, 398: 124192.
[7]	何春明, 陈红军, 刘超, 等. 高温合成聚合物压裂液体系研究[J]. 油田化学, 2012, 29 (1): 65-68.
[8]	安志伟. 电絮凝中不同铁基电极对压裂返排液除硼过程的机理及实验研究[D]. 天津: 河北工业大学, 2021.
[9]	郝振兴. 油田压裂技术分析与压裂液优化[J]. 化学工程与装备, 2023 (3): 38-39.
[10]	郝伟. 耐高温交联酸体系改性及破胶性能实验研究[D]. 成都: 成都理工大学, 2020.
[11]	孙井泉. 抗高温低摩阻硼交联加重压裂液研究[D]. 成都: 西南石油大学, 2022.
[12]	兰健, 戴姗姗, 戴元梅, 等. 耐高温酸液稠化剂的合成与性能评价[J]. 油田化学, 2023, 40 (4): 636-642.
[13]	罗志锋, 张浩飞, 赵立强, 等. 耐200 ℃高温、低伤害压裂液稠化剂[J]. 油田化学, 2024: 1-11.
[14]	周亚峰, 杨江, 刘海玲, 等. 耐温耐盐两性聚丙烯酰胺稠化剂的制备及其性能[J]. 油田化学, 2024, 41 (1): 19-25, 60.
[15]	Lenji M A, Haghshenasfard M, Sefti M V, et al. Numerical modeling and experimental investigation of inorganic and organic crosslinkers effects on polymer gel properties[J]. Journal of Petroleum Science and Engineering, 2018, 160: 160-169.
[16]	冯颖, 解玉鞠, 崔倩, 等. 壳聚糖及其改性膜的研究进展及在水处理领域的应用[J]. 水处理技术, 2023, 49 (12): 76-82. doi: 10.16796/j.cnki.1000-3770.2023.12.014
[17]	Khan M. Chemical and physical architecture of macromolecular gels for fracturing fluid applications in the oil and gas industry; current status, challenges, and prospects[J]. Gels, 2024, 10 (5): 338.
[18]	何丹丹, 赖璐. 油气田废水配制水基压裂液技术研究进展[J]. 工业水处理, 2024: 1-17.
[19]	李必智. 疏水缔合聚合物压裂液的制备及性能评价[J]. 当代化工, 2024, 53 (7): 1590-1594, 1599.
[20]	Thakur S, Arotiba O. Synthesis, characterization and adsorption studies of an acrylic acid-grafted sodium alginate-based TiO₂ hydrogel nanocomposite[J]. Adsorption Science & Technology, 2018, 36 (1-2): 458-477.
[21]	李楠, 高党鸽, 吕斌, 等. 皮胶原在柔性智能可穿戴领域的研究进展[J]. 化工进展, 2024, 43 (5): 2645-2660. doi: 10.16085/j.issn.1000-6613.2023-2119
[22]	Cook B A, Bonino C A, Trainham J A. Solid-state processing of oxidation-resistant molybdenum borosilicide composites for ultra-high-temperature applications[J]. Journal of Materials Science, 2014, 49 (22): 7750-7759.
[23]	Zhang S C, Hilmas G E, Fahrenholtz W G. Pressureless densification of zirconium diboride with boron carbide additions[J]. Journal of the American Ceramic Society, 2006, 89 (5): 1544-1550.

w（氧氯化锆）/%	w（四硼酸钠）/%	产物外观	交联状态	凝胶黏度/ （mPa·s）
2	1.5	无白色沉淀	不可挑挂	253.63
3	2	无白色沉淀	不可挑挂	266.97
5	2	无白色沉淀	部分可挑挂	304.12
5	2.5	无白色沉淀	可挑挂	356.64
5	3	有白色沉淀	可挑挂	365.44
6	3	有白色沉淀	可挑挂	352.26

pH值	凝胶黏度/ （mPa·s）	产物外观	交联状态
0.5	376.86	透明，无沉淀	能挑挂
1	322.78	透明，无沉淀	部分能挑挂
2	294.16	透明，微量沉淀	不能挑挂
3	266.36	透明，微量沉淀	不能挑挂

Synthesis and crosslinking properties of W-SN crosslinking agent

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