基于片状ZnO的功效性紫外屏蔽材料的制备及性能研究

doi:10.3969/j.issn.2097-2806.2025.01.007

Abstract

Abstract:

With flaky zinc oxide （F-ZnO） as the core, SiO₂ was used to coat the surface of F-ZnO to obtain SiO₂/F-ZnO （SFZ）. Then Pro/SiO₂/F-ZnO （PSFZ） was prepared by loading proanthocyanidins （Pro） on SFZ composites. The samples were characterized by FTIR, XRD, TEM, UV and TGA. The results showed that SiO₂ uniformly coated on the surface of flake-shaped ZnO particles in amorphous form, and the appropriate coating amount was 15%. Proanthocyanidins formed a uniform layer on the SFZ surface with a suitable loading amount of 20%. The efficacy was evaluated by antioxidant test and in vitro skin-whitening test, and the stability was evaluated by application in the basic formula. The results showed that PSFZ had good free radical scavenging ability and tyrosinase inhibiting ability. In the testing of sun protection indexes, PSFZ composite had better UV-shielding effect than SFZ. The composite still had high stability under the conditions of formulation application and UV irradiation.

Key words: ZnO flake, SiO₂, proanthocyanidins, UV shielding, efficacy

CLC Number:

TQ658

Xiaomin Sun, Shixiang Zuo, Yaoyao Yu, Xin Wu, Yue Cai, Chao Yao. Preparation and properties of effective UV-shielding materials based on flake-shaped ZnO[J].China Surfactant Detergent & Cosmetics, 2025, 55(1): 55-62.

Figures/Tables 14

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References 22

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SFZ-X	等电点	SFZ-X	等电点
SFZ-0	9.32	SFZ-15	2.14
SFZ-5	7.82	SFZ-20	2.12
SFZ-10	5.17	SFZ-25	2.14

名称	ZnO	F-ZnO	SFZ	PSFZ
SPF	4.49	4.79	4.04	6.63
PFA	3.52	4.61	3.80	5.28
PAindex	+	++	+	++
λc	372.2	377.5	376.3	377.9

	OD₂₈₀	ρ（Pro）/（μg/mL）	保留率/%
F1	0.002	—	—
F2	0.055	1.17	94.15
F3	0.543	15.87	20.65

Preparation and properties of effective UV-shielding materials based on flake-shaped ZnO

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防晒乳名称	m（甘油）/g	m（单硬脂酸甘油酯）/g	m（SFZ）/g	m（Pro）/g	m（PSFZ）/g	m（水）/g	m（总量）/g
F1	11	35	10			44	100
F2	11	35			10	44	100
F3	11	35	8	2		44	100