多阳离子位点季铵盐与AEC复配体系的应用性能研究

doi:10.3969/j.issn.2097-2806.2024.02.002

Abstract

Abstract:

A quaternary ammonium surfactant （TC-GS） containing multiple cationic sites was mixed with sodium fatty alcohol polyoxyethylene ether carboxylate （AE₉C） in different ratios, and the wetting, detergency, emulsification, antistatic and activated-carbon-dispersing properties of the mixed systems were tested. The results showed that the TC-GS/AE₉C system was homogeneous and transparent solution at different mixing ratios, indicative of excellent compatibility and stability. The mixed system showed better wetting ability for canvas cloth than single surfactant, with the best wetting performance at α_TC-GS of 0.4. The mixed surfactants showed synergistic effect in the process of emulsifying liquid paraffin. The AE₉C solution had good detergency for both carbon-black-stained cloth and grease-stained cloth, but the detergency was decreased after mixed with TC-GS, probably due to the adsorption of TC-GS on the surface of stained cloths, which hindered the washing and stripping of stains. Both TC-GS solution and the solution of TC-GS/AE₉C system exhibited good antistatic performance and could reduce the surface resistance of polyester fabric to≤10¹⁰ Ω. The TC-GS/AE₉C system at most mixing ratios had good ability to disperse activated carbon; however, when the mixing ratio was consistent with the theoretical isoelectric molar ratio, the mixture had poor dispersion stability for activated carbon.

Key words: quaternary ammonium salt, sodium fatty alcohol polyoxyethylene ether carboxylate, compounding, application property

CLC Number:

TQ423

Shida Hou, Zhifei Wang, Yakui Wang, Jun Li, Yajie Jiang, Tao Geng. Application properties of the mixed system of AEC and a quaternary ammonium salt with multiple cationic sites[J].China Surfactant Detergent & Cosmetics, 2024, 54(2): 131-138.

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References 29

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Sample		R_s/Ω	ρ_s/Ω	lg（R_s/Ω）	Δlg（R_s/Ω）
	Blank	3.09×10¹⁴	2.56×10¹⁶	14.49
α_TC-GS	1.0	4.74×10⁹	3.86×10¹¹	9.68	4.81
	0.8	7.73×10⁹	6.29×10¹¹	9.89	4.60
	0.6	8.10×10⁹	6.59×10¹¹	9.91	4.58
	0.5	2.06×10¹⁰	1.67×10¹²	10.31	4.18
	0.4	2.01×10¹⁰	1.64×10¹²	10.30	4.19
	0.2	2.39×10¹⁰	1.95×10¹²	10.38	4.11
	0	5.51×10¹¹	4.48×10¹³	11.74	2.75

Application properties of the mixed system of AEC and a quaternary ammonium salt with multiple cationic sites

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