松香基双子表面活性剂合成及应用进展

doi:10.3969/j.issn.1001-1803.2022.08.015

Abstract

Abstract:

It is necessary to develop environment-friendly and sustainable surfactants owing to the more and more attention to environment, ecology and sustainable development and the rapid reduction of petroleum resources. Rosin is an important natural chemical raw material, which is non-toxic, renewable, and widely used. Rosin-based gemini surfactants are mainly synthesized from abietic acid and its derivatives, which belong to bio-based surfactants. They are green, environment-friendly and have good surface activity and good biodegradability. Their design and synthesis, performance test and application development have become research hotspots. According to the different properties of headgroups, rosin-based gemini surfactants are classified into anionic, cationic, amphoteric and non-ionic types. In this review, the research progress of rosin-based gemini surfactants in recent years is summarized. The performance of rosin-based gemini surfactants is discussed. The synthetic methods, performance characteristics and application of various rosin-based gemini surfactants are briefly described. The development trend of rosin-based gemini surfactants is also prospected.

Key words: rosin base, gemini surfactant, green, synthesis, application

CLC Number:

TQ423

Zhao Shufen,Zheng Danmiao,Liu Huaxi,Song Songlin,Chen Zhan,Yang Ningyuan,Wei Xingchuan. Progress in synthesis and application of rosin based gemini surfactants[J].China Surfactant Detergent & Cosmetics, 2022, 52(8): 892-903.

Figures/Tables 23

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References 31

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化合物	cmc/（mol/L）	γ_cmc/（mN/m）	Krafft/℃	泡沫高度H₀/H_{5 min}	乳化时间/min	HLB
1	1.3×10^-4	28.1	<0	2/0	0.3	14.9
2	1.1×10^-4	33.6		5/3	>30	12.21
5	1.38×10^-3	31.8	50~60	19/3.5	2.55	9.9
6	1.71×10^-3	33.2	50~60	23/11.5	1.6	7.6
7	8.63×10^-5	23.5	19	115/97	55
K12	8.1×10^-3	33	10	175/170	12

化合物	cmc/（mol/L）	γ_cmc/（mN/m）	泡沫高度H₀/H_{5 min}	乳化时间
8	2×10^-5	23.7	40/2	4 d
9	6.7×10^-6	24	115/110	8 min
10	1.42×10^-4	36.69	200/150	16 min
11	4×10^-4	37.35	255/250	20 min
12	6×10^-4	36.63	252/250	25 min
15	2.3×10^-5	32	70/53	47 min
16	2.3×10^-5	32	60/52	34 min
17	4.1×10^-4	38.4
18	1.1×10^-4	36.4
19	3.32×10^-5	24.7	137/125	42 min
22	3.9×10^-4	39.18		36 min
23	7.5×10^-4	45.02		245 s
26	4.4×10^-4	34.3
CTAB	9.8×10^-4	37.3	122/116	159 s

化合物	cmc/（mol/L）	γ_cmc/（mN/m）	泡沫高度H₀/H_{5 min}	乳化时间/s	浊点/℃	HLB
28	6.5×10^-4	34.3	2/0	50	76.9	18.1
29	1.9×10^-4	22.2		200	>90
30	1×10^-4	37.8	105/41			16.8
31	3.46×10^-3	48.2	16/6	11	>90	5.8
TX-10	2.03×10^-3	31.6		165	63

Progress in synthesis and application of rosin based gemini surfactants

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