磁性纳米Fe3O4吸附材料的制备及在废水处理中的应用

doi:10.3969/j.issn.1001-1803.2022.08.014

Abstract

Abstract:

With the acceleration of industrialization, a large amount of wastewater containing emulsions, dyes, and refractory organics have been discharged, causing irreversible harm to both human beings and nature. Therefore, it is of great significance to develop an adsorbent with large adsorption capacity and good separation effect for wastewater treatment. Magnetic nano-Fe₃O₄, with the advantages of good selectivity, rapid separation and being recyclable, has been widely concerned by scientists and engineers for its promising application. Herein, the preparation methods of magnetic nano-Fe₃O₄ adsorbents and the modified nano-Fe₃O₄ containing specific functional groups are introduced. The adsorption mechanism of magnetic composite materials is concluded by tracing the research trends in actual wastewater application. It is suggested that the preparation of magnetic nanomaterials should be further optimized in order to meet the needs of different wastewater, and more efficient and more widely applicable compounds should be developed to reduce the impact on environment, and to increase their desorption regeneration performance and improve recycling efficiency.

Key words: magnetic, adsorption, wastewater treatment, adsorption mechanism

CLC Number:

X789

Zhao Fengtao,Li Xuanjing,Li Enze,Du Zhiping,Li Jianfeng,Shen Jing. Preparation of magnetic nano-Fe₃O₄and its application in wastewater treatment[J].China Surfactant Detergent & Cosmetics, 2022, 52(8): 882-891.

Figures/Tables 3

Fig. 1

Fig. 2

Tab. 1

References 49

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污染物种类	吸附剂	污染物	吸附容量	最优条件	来源
染料废水	Fe₃O₄@SiO₂@CCS	Rhb	191.57 mg/g	T=298 K	[29]
	Fe₃O₄-CS	腐殖酸（HA）	44.84 mg/g	pH=4	[12]
	Fe₃O₄/MgAl-LDH	活性红（RR）刚果红（CR）酸性红1（AR1）	97 mg/g 253 mg/g 52 mg/g	pH=2~10 T=298 K	[30]
	Fe₃C/C	铬黑T 溴酚蓝（BPB）溴甲酚绿（BCG）荧光素（FLU）	2 105 mg/g 1 899 mg/g 2 007 mg/g 1 976 mg/g		[31]
	磁性多壁碳纳米管	结晶紫（CV）硫堇（Th）健那绿（JG）亚甲基蓝（MB）	227.7 mg/g 250.0 mg/g 36.4 mg/g 48.1 mg/g	pH=7	[39]
	乙二胺改性的磁性壳聚糖纳米粒子（EMCN）	酸橙7 酸橙10	3.47 mmol/g 2.25 mmol/g	pH=3 pH=4 T=298 K	[40]
有机污染物	磁性炭材料（NMC）	TCN	48.35 mg/g	pH=6.8	[32]
	磁性杏仁壳活性炭	三硝基苯酚（TNP）	70.83 mg/g	pH=2 T=298 K	[33]
	胺化β-环糊精官能化的Fe₃O₄	萘普生（CBZ）卡马西平（NAP）双酚A（BPA）	1.304 mg/g 1.074 mg/g 0.899 mg/g	pH=7 T=298 K	[41]
	WSBC/Fe₃O₄ PSBC/Fe₃O₄	磷酸二铵	217.39 mg/g 212.77 mg/g	pH=4 T=298 K	[34]
乳液废水	Fe₃O₄/SiO₂-APTES Fe₃O₄/SiO₂-QC	乳化油		pH=4~7	[20]
	Fe₃O₄@APFS	乳化油		pH=7	[23]
	EP@APTES-Fe₃O₄	乳化油		pH=2~6	[36]
	Fe₃O₄@CS@NaOL	乳化油		pH=4	[37]

Preparation of magnetic nano-Fe₃O₄and its application in wastewater treatment

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Preparation of magnetic nano-Fe3O4 and its application in wastewater treatment

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Preparation of magnetic nano-Fe₃O₄and its application in wastewater treatment