羟乙基纤维素和γ-聚谷氨酸混合体系的流变行为及协同机理

doi:10.3969/j.issn.1001-1803.2022.06.001

Abstract

Abstract:

The rheological properties of the mixed system of hydroxyethyl cellulose （HEC） and γ-polyglutamic acid （γ-PGA） were systematically studied by investigating the apparent viscosity, flow curves, viscoelasticity, viscosity-temperature curves and other rheological properties. The microstructure of the mixed system of HEC and γ-PGA was also characterized. The experimental results showed that HEC and γ-PGA had synergistic effect of increasing viscosity at different mass ratios when the total mass fraction of HEC and γ-PGA was 1.2%, in which the synergistic effect of increasing viscosity was most obvious when the mass ratio of HEC/γ-PGA was 2∶1. Single HEC system, single γ-PGA system and mixed HEC/γ-PGA system were all shear thinning fluids, and their flow curves could be well fitted by Cross equation, and the correlation coefficients （R） were all greater than 0.999. Compared with the single systems of HEC and γ-PGA, the range of linear viscoelastic region of the mixed HEC/γ-PGA system increased, i.e., the overall strain resistance of the mixed HEC/γ-PGA system was enhanced. In frequency scanning, the intersection of elastic modulus （G'） and viscous modulus （G''） of HEC and γ-PGA mixtures moved to the low frequency direction, indicating that the mixed system was more elastic than the single system. Meanwhile, with the increase of temperature, the apparent viscosities of single HEC, single γ-PGA and mixed HEC/γ-PGA systems were decreased to varying extent. The viscosity-temperature curves of these systems could be well fitted by the Arrhenius equation, and the correlation coefficients were greater than 0.996. For the mixed HEC/γ-PGA system, the elastic feature was dominant when the temperature was lower than 45 ℃, while the viscous feature was dominant when the temperature was higher than 45 ℃. In addition, the physical entanglement and three-dimensional network structure were strengthened after mixing HEC and γ-PGA, as shown in microstructure observation.

Key words: hydroxyethyl cellulose, γ-polyglutamic acid, rheological behavior, synergistic mechanism

CLC Number:

TQ658

Chen Hanjun,Zhuang Jie,Wu Xu,Shen Xingliang,Zhang Wanping,Zhang Qianjie. Rheological behavior and synergistic mechanism of the mixed system of hydroxyethyl cellulose and γ-polyglutamic acid[J].China Surfactant Detergent & Cosmetics, 2022, 52(6): 577-584.

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References 25

[1]	Chorin A. Numerical solution of the Navier-Stokes equations[J]. Mathematics of Computation, 1968, 22 (104) : 745-762. doi: 10.1090/S0025-5718-1968-0242392-2
[2]	Jia Hongjiao, Li Fangfang, Miao Yulian, et al. Application and research progress of rheology in the field of cosmetics[J]. China Surfactant Detergent & Cosmetics, 2014, 44 (8) : 467-471.
[3]	Kusakari K, Yoshida M, Matsuzaki F, et al. Evaluation of post-application rheological changes in cosmetics using a novel measuring device: relationship to sensory evaluation[J]. Journal of Cosmetic Science, 2003, 54 (4) : 321-33. pmid: 14528386
[4]	Luan Tu. Study on the molecular characterization rheological properities and physical cryogel of mucopolysaccharide hyaluronan[D]. Shanghai: Shanghai Jiao Tong University, 2011.
[5]	Hu Zizi. Effects of γ-polyglutamic acid on gelation and structural properties of fish gelatin[D]. Jiangxi: Jiangxi Normal University, 2019.
[6]	Luo Shiying. Study on rheological properties of hydroxyethyl cellulose in aqueous solution[D]. Hubei: Central China Normal University, 2016.
[7]	Jilal I, Barkany S E, Bahari Z, et al. New quaternized cellulose based on hydroxyethyl cellulose (HEC) grafted EDTA: Synthesis, characterization and application for Pb (II) and Cu (II) removal[J]. Carbohydrate Polymers, 2018, 180 (15) : 156-167. doi: 10.1016/j.carbpol.2017.10.012
[8]	Zheng Wenjie, Ye Jun, Xiong Jian. Research progress of rheological behavior of modified hydroxyethyl cellulose solutions[J]. Chemical Industry and Engineering Progress, 2007, 26 (5) : 636-641.
[9]	Patruyo L G, Mullera A J, Saez A E. Shear and extensional rheology of solutions of modified hydroxyethyl celluloses and sodium dodecyl sulfate[J]. Polymer, 2002, 43: 6481-6493. doi: 10.1016/S0032-3861(02)00598-0
[10]	Tanaka R, Meadows J, Williams P A, et al. Interaction of hydrophobically modified (hydroxyethy1) cellulose with various added surfactants[J]. Macromolecules, 1992, 25: 1304-1310. doi: 10.1021/ma00030a016
[11]	Ogunleye A, Bhat A, Irorere V U, et al. Poly-γ-glutamic acid-production, properties and applications[J]. Microbiology, 2015, 161: 1-17. doi: 10.1099/mic.0.081448-0 pmid: 25288645
[12]	Liu Xia, Liu Fei, Liu Shaoying, et al. Moisture retention capacity and safety evaluation of poly-γ-glutamat[J]. China Surfactant Detergent & Cosmetics, 2015, 45 (5) : 275-278.
[13]	Kim H G, Kim K S, Oh T H. Anti-inflammatory effects of poly-γ-glutamic acid on DNCB-induced allergic contact dermatitis in dogs[J]. Journal of Veterinary Clinics, 2012, 29 (4) : 283-296.
[14]	Liu X, Liu F, Liu S, et al. Poly-γ-glutamate from Bacillus subtilis inhibits tyrosinase activity and melanogenesis[J]. Applied Microbiology and Biotechnology, 2013, 97 (22) : 9801-9809. doi: 10.1007/s00253-013-5254-6
[15]	Chen W X, Piao Q, Cui Z J, et al. Hyaluronidase inhibitors containing the active component poly-γ-glutamate: CN101304724A[P]. 2008-11-12.
[16]	Jiang Tong, Zhang Chen, Zhang Zhiwei, et al. Study on rheological properties and melting sensation of O/W cream[J]. China Surfactant Detergent & Cosmetics, 2019, 49 (11) : 705-710.
[17]	Zheng Wenjie, Ye Jun, He Wanfen, et al. The rehological behavior of HEC aqueous solution[J]. Paper Science & Technology, 2007, 26 (1) : 40-42.
[18]	Qiu Bingyi. Rheological properties of cosmetics and detergents[M]. Beijing: Chemical Industry Press, 2003.
[19]	Fan Yichao, Xie Xinhua, Shen Yue, et al. Effect of poly-γ-glutamic acid on the pasting and rheological properties of wheat starch[J]. Journal of the Chinese Cereals and Oils Association, 2019, 34 (5) : 33-37.
[20]	Fan Yue, Chen Qiang, Jin Hao, et al. Application research of rheological properties in emulsifying process conditions[J]. China Surfactant Detergent & Cosmetics, 2018, 48 (10) : 577-581.
[21]	Chun M S, Kim C, Lee D E. Conformation and translational diffusion of a xanthan polyelectrolyte chain: Brownian dynamics simulation and single molecule tracking[J]. Physical Review E, 2009, 79 (1) : 51-91.
[22]	Jung D, Kruse A. Evaluation of Arrhenius-type overall kinetic equations for hydrothermal carbonization[J]. Journal of Analytical and Applied Pyrolysis, 2017, 127: 286-291. doi: 10.1016/j.jaap.2017.07.023
[23]	Lazaridou A, Vaikousi H, Biliaderis C G, et al. Effects of polyols on cryostructurization of barley β-glucans[J]. Food Hydrocolloids, 2008, 22 (2) : 263-277. doi: 10.1016/j.foodhyd.2006.11.012
[24]	Briscoe B, Luckham P, Zhu S. The effects of hydrogen bonding upon the viscosity of aqueous poly(vinyl alcohol) solutions[J]. Polymer, 2000, 41 (10) : 3851-3860. doi: 10.1016/S0032-3861(99)00550-9
[25]	Hu Z Z, Sha X M, Ye Y H, et al. Effects of γ-polyglutamic acid on the gelling properties and non-covalent interactions of fish gelatin[J]. 2020, 51 (3) : 511-520.

样品类型	λ/s	η₀/（Pa·s）	η_∞/（Pa·s）	m	R
0.8% HEC+0.4% γ-PGA	29.52	94.05	0.26	0.62	0.999 95
0.8% HEC	1.07	3.69	0.06	0.54	0.999 66
0.4% γ-PGA	0.96	1.83	0.05	0.48	0.999 25

Rheological behavior and synergistic mechanism of the mixed system of hydroxyethyl cellulose and γ-polyglutamic acid

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