火山矿泥Pickering乳液的制备及其pH稳定性

doi:10.3969/j.issn.1001-1803.2021.06.006

Abstract

Abstract:

Taking Wudalianchi volcano mud particles as emulsifier, olive oil as oil phase and deionized water as water phase, the preparation process of volcano mud Pickering emulsion was optimized by L₉（3 ⁴） orthogonal experiment. The particle size, microstructure and Zeta potential of the emulsion were analyzed, and the pH stability was studied. The results show that stable Pickering emulsion could be prepared by high-pressure （80 MPa）homogenization at 40 ℃ according to the formula in which the mass fractions of olive oil, volcano mud particles and deionized water are 20%, 3% and 77%, respectively. The average particle size of the emulsion is （10.516±0.141） μm. Clear, intact and uniform spherical emulsion particles are observed by Cryo-SEM. The average Zeta potential is -55.01 mV. The emulsion exhibits no creaming in the pH range of 4-12, and demulsification has not been observed in the pH range of 1-14. The volcano mud particles are both hydrophilic and lipophilic. The Pickering emulsion with olive oil as oil phase can be stabilized with volcano mud particles without addition of other chemicals, and the emulsion has excellent pH stability.

Key words: Wudalianchi, volcano mud, Pickering emulsion, preparation process, pH stability

CLC Number:

TQ658

FANG Zhen-xing,WANG Xi-ying,WU Jing,ZENG Ying,PAN Hong,XIE Zhen-hua. Preparation of Pickering emulsion from volcano mud and its pH stability[J].China Surfactant Detergent & Cosmetics, 2021, 51(6): 506-512.

Figures/Tables 10

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References 24

[1]	Shi Xuan, Xing Xiaokai, Lei Yiting, et al. Research progress on the stability of Pickering emulsion[J]. Speciality Petrochemicals, 2020,37(1): 65-71.
[2]	Yu Mingying, Wang Jing, Yang Cheng, et al. Advances in the applications of Pickering emulsion in cosmetics[J]. China Surfactant Detergent ＆ Cosmetics, 2019,49(6): 398-402.
[3]	Xie Jin, Luo Yijing, Liu Yang, et al. Pickering emulsion technology and its application progress in volatile oil of Chinese materia medica[J]. Chinese Traditional and Herbal Drugs, 2020,51(5): 1343-1349.
[4]	Zhang Jifen, Wang Yanhua, Li Qingqing, et al. Research progress of Pickering emulsion drug delivery systems[J]. Acta Pharmaceutica Sinica, 2019,54(12): 2232-2239.
[5]	Wang Weihao, Yang Xin, Li fei, et al. E@Alg@s-TiO₂ microsphere stabilized O/W Pickering emulsion and the enhancement of interfacial enzymatic catalysis[J]. Journal of Chemical Industry and Engineering (China), 2019,70(12): 4777-4786.
[6]	Tian Xuwang, Ge Xiaohui, Shi Xingbo, et al. Advances in the application of nanocellulose in Pickering emulsion preparation[J]. China Surfactant Detergent ＆ Cosmetics, 2020,50(3): 194-198, 203.
[7]	Yang Zeyu, Wang Wanxu, Wang Guoyong, et al. Preparation of modified montmorillonite by BS-12 and application in Pickering emulsion[J]. China Surfactant Detergent ＆ Cosmetics, 2020,50(3): 177-181.
[8]	Ning Fangjian, Ge Zhenzhen, Qiu Liang, et al. Double-induced se-enriched peanut protein nanoparticles preparation, characterization and stabilized food-grade pickering emulsions[J]. Food Hydrocolloids, 2020,99:105308. doi: 10.1016/j.foodhyd.2019.105308
[9]	Ren Zhongyang, Chen Zhongzheng, Zhang Yuanyuan, et al. Novel food-grade Pickering emulsions stabilized by tea water-insoluble protein nanoparticles from tea residues[J]. Food Hydrocolloids, 2019,96:322-330. doi: 10.1016/j.foodhyd.2019.05.015
[10]	Ali M, Berthold W, Nabilah A, et al. In vitro intestinal lipolysis of emulsions based on starch granule Pickering stabilization[J]. Food Hydrocolloids, 2019,95:468-475. doi: 10.1016/j.foodhyd.2019.04.051
[11]	Worthen A, Foster L, Dong J, et al. Synergistic formation and stabilization of oil-in-water emulsions by a weakly interacting mixture of zwitterionic surfactant and silica nanoparticles[J]. Langmuir, 2014,30(4): 984-994. doi: 10.1021/la404132p pmid: 24409832
[12]	Hu Deping, Zhang Xueqin, Dai Zihao, et al. Preparation of modified montmorillonite and its function for stabilizing Pickering emulsions in cooperation with alginic acid derivative[J]. China Surfactant Detergent ＆ Cosmetics, 2017,47(11): 627-632.
[13]	Li Lei, Zhang Qiaoling, Liu Youzhi, et al. Fabrication and factors of stabilization of Pickering emulsion based on TiO₂-SA-Arg nanoparticles[J]. Polymer Materials Science and Engineering, 2016,32(8): 162-170.
[14]	Zhang M, Wang A, Li J, et al. Factors influencing the stability and type of hydroxyapatite stabilized Pickering emulsion[J]. Materials Science & Engineering C, Materials for Biological Applications, 2017,1(70): 396-404.
[15]	Lv Yuqi, Bai Jie, Ni Xiaohu, et al. Effects of Wudalianchi slime on anti inflammation and hair growth[J]. Chinese Traditional and Herbal Drugs, 2000 (4): 43-45.
[16]	Gao Fengqing, Wang Hong, Li Xia, et al. Discussion on the treatment of arthritis with Wudalianchi mineral spring mud therapy[J]. Acta Chinese Medicine and Pharmacology, 2011,39(2): 97-98.
[17]	Guo Xinming. Effect of trace elements in Wudalianchi volcanic mud on skin[J]. Studies of Trace Elements and Health, 2008 (2): 61-62.
[18]	Wang Xiying, Xie Zhenhua, Fang Zhenxing. Application of Wudalianchi volcanic mineral mud in cosmetics[J]. Detergent & Cosmetics, 2014,37(8): 26-29.
[19]	Wang Xiying, Fang Zhenxing, Wu Jing, et al. The preparation technology of clean mud film of Wudalianchi mud[J]. Heilongjiang Science, 2019,10(24): 41-43.
[20]	Fang Zhenxing, Wang XiYing, Wu jing, et al. Study on preparation of Wudalianchi mineral elderberry eye cream[J]. Flavour Fragrance Cosmetics, 2019 (5): 52-54.
[21]	Fang Zhenxing, Xie Zhenhua, Wang Xiying, et al. Study on the preparation process of the mud cleansing gel[J]. Heilongjiang Science, 2016,7(18): 4-5.
[22]	Fang Zhenxing, Wu Jing, Zeng Ying, et al. Longitudinal variation trend of soil particle size in volcano mud area of Yaoquanshan,Wudalianchi[J]. Heilongjiang Science, 2020,11(2): 44-45.
[23]	Dong Xiao, Huang Guoqing, Xiao Junxia, et al. Research on preparation and oxidation stability of grape Seed oil microcapsules[J]. China Condiment, 2020,45(5): 88-93.
[24]	Huang Jianzhao, Li Pan, Xu Jinwei, et al. Study on the preparation and stability of sacha inchi oil nanoemulsions[J]. Food and Fermentation Industries, 2020,46(11): 216-222.

水平	A	B	C	D（空）	φ（乳液相）/%
1	1	1	1	1	54.86
2	1	2	2	2	76.10
3	1	3	3	3	55.75
4	2	1	2	3	71.68
5	2	2	3	1	100.00
6	2	3	1	2	94.69
7	3	1	3	2	49.55
8	3	2	1	3	77.87
9	3	3	2	1	61.06
k₁	62.24	58.70	75.81	71.97
k₂	88.79	84.66	69.61	73.45
k₃	62.83	70.50	68.43	68.43
R	26.55	25.96	7.38	5.02

方差来源	离差平方和	自由度	均方	F比值	P值	显著性
A	1 379.52	2	689.76	34.63	< 0.05	显著
B	1 013.65	2	506.83	25.44	< 0.05	显著
C	94.11	2	47.06	2.36	> 0.05	不显著
误差	39.83	2	19.92

Preparation of Pickering emulsion from volcano mud and its pH stability

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References 24

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pH值	乳析指数
pH值	0.5 h	1 h	2 h	3 h	6 h	12 h	24 h
1	100	89.61±2.35	83.67±1.98	79.55±0.58	65.32±0.61	44.56±0.73	31.65±0.35
2	100	100	85.39±2.67	84.12±1.33	69.44±0.86	48.45±0.64	39.28±1.43
3	100	100	100	100	85.32±2.15	62.97±0.91	49.61±0.36
4	100	100	100	100	100	100	100
5	100	100	100	100	100	100	100
6	100	100	100	100	100	100	100
7	100	100	100	100	100	100	100
8	100	100	100	100	100	100	100
9	100	100	100	100	100	100	100
10	100	100	100	100	100	100	100
11	100	100	100	100	100	100	100
12	100	100	100	100	100	100	100
13	36.59±0.54	28.30±0.98	25.96±0.30	24.53±0.25	22.21±0.19	19.86±0.27	15.34±0.28
14	26.88±0.89	24.07±0.49	18.49±0.11	16.94±0.31	14.32±0.36	12.56±0.11	10.11±0.35

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水平	A w（油相）/%	B w（乳化颗粒）/%	C 均质压力/MPa
1	10	1	80
2	20	3	100
3	30	6	120