聚醚有机硅表面活性剂与经典阴离子表面活性剂复配体系

doi:10.3969/j.issn.2097-2806.2024.10.002

Abstract

Abstract:

Polyether organosilicon surfactants have received widespread attention in recent years due to their excellent surface activities. To further expand the downstream application and develop a surfactant formula, in this work, a polyether modified trisiloxane surfactant was mixed with a classical anionic surfactant （alkyl glycoside sulfonate or fatty-alcohol polyethoxylate phosphate）, and the mixed adsorption parameters and mixed micellization parameters of the binary surfactant mixtures were investigated in detail. For the selected mixing ratio, the dispersing performance of binary surfactant mixtures was evaluated in common model systems （foam, emulsion, suspension）, which could provide an important reference for the application and development of systems of polyether modified silicone surfactants.

Key words: surface activity, mixture of anionic and nonionic surfactants, dispersion

CLC Number:

TQ423

Xinzhi Liang, Ting Sun, Xinyao Ye, Yukai Wang, Liang Bai, Hongguang Li. Study on the mixed systems of polyether organosilicon surfactant and classic anionic surfactants[J].China Surfactant Detergent & Cosmetics, 2024, 54(10): 1155-1165.

Figures/Tables 11

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References 32

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	α₁^*	cmc/ （mol/L）	γ_cmc/ （mN/m）	pc₂₀	Г_max/ （μmol/m²）	A_min/nm²	cmc _ideal/ （mol/L）	Γ_{max, ideal}/ （μmol/m²）	A_{min, ideal}/nm²
APG-SS/PTS	1	4.15×10^-4	31.78	3.15	4.58	0.36
	0.8	3.56×10^-4	25.46	5.12	2.68	0.62	3.067×10^-4	2.99	0.55
	0.5	3.18×10^-4	21.97	5.22	2.29	0.73	2.204×10^-4	2.85	0.58
	0.2	1.85×10^-4	21.79	5.39	2.37	0.70	1.720×10^-4	2.75	0.60
	0	1.50×10^-4	21.42	5.58	2.48	0.67
AEP-K/PTS	1	3.05×10^-5	39.91	5.26	3.34	0.50
	0.8	3.89×10^-5	39.70	5.04	3.47	0.48	3.594×10^-5	3.001 8	0.55
	0.5	4.49×10^-5	38.96	5.20	1.98	0.84	5.028×10^-5	2.595 0	0.64
	0.2	1.14×10^-4	30.91	5.31	2.19	0.76	8.364×10^-5	2.564 1	0.65
	0	1.50×10^-4	21.42	5.58	2.48	0.67

	α₁^*	X^m₁	β^m	f ^m₁	f ^m₂	X^σ₁	β^σ	f ^σ₁	f ^σ₂
APG-SS/PTS	0.8	0.562	-4.970	0.386	0.208	0.373	-7.593	0.051	0.347
	0.5	0.209	-4.035	0.080	0.839	0.285	-8.642	0.012	0.495
	0.2	0.190	-6.214	0.017	0.799	0.212	-9.535	0.003	0.652
AEP-K/PTS	0.8	0.752	-8.122	0.608	0.010	0.678	-2.632	0.761	0.299
	0.5	0.678	-6.601	0.504	0.048	0.172	-4.217	0.056	0.882
	0.2	0.547	-4.310	0.413	0.275	0.127	-6.044	0.010	0.907

	α₁	ΔG_{mic, ideal}/ （KJ/mol）	ΔG_mic/ （KJ/mol）	ΔH_mic/ （KJ/mol）	TΔS_mic/ （KJ/mol）
APG-SS/PTS	0.8	-1.699	-4.731	-3.032	1.699
	0.5	-1.270	-2.923	-1.653	1.270
	0.2	-1.205	-3.574	-2.369	1.205
AEP-K/PTS	0.8	-1.387	-5.137	-3.75	1.387
	0.5	-1.558	-5.132	-3.574	1.558
	0.2	-1.707	-4.354	-2.647	1.707

样品名称	n	t^*/s	t_i/s	t_m/s	R_1/2/（mN/（m·s））
APG-SS/PTS	0.352	0.372	5.37×10^-4	258	50.86
AEP-K/PTS	0.417	0.023	9.41×10^-5	5.89	804.78

Study on the mixed systems of polyether organosilicon surfactant and classic anionic surfactants

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