不同酯化度烷基糖苷磺基琥珀酸酯盐的合成与性能

doi:10.3969/j.issn.2097-2806.2023.07.005

Abstract

Abstract:

Four products of alkyl polyglucoside sulfosuccinates （APGSS） with different degrees of esterification were synthesized by two-step method. The synthesis conditions of APGSS with different degrees of esterification were optimized by investigating the influences of reaction time and molar ratio on the yields of APGSS. In addition, the foaming properties, emulsifying properties and wetting properties of APGSS with different degrees of esterification were investigated. The results showed that, the foaming properties of APGSS decreased with the increase of esterification degree both in distilled water and hard water, and the foam stability thereof was better than that of alkyl polyglucoside （APG）; the emulsifying performance of all APGSS for soybean oil was better than that for liquid paraffin. With the increase of the degree of esterification, the wetting ability gradually decreased.

Key words: alkyl polyglycoside, alkyl polyglycoside sulfosuccinate, synthesis process, foaming ability, emulsifying property, wetting

CLC Number:

TQ423

Zhou Yuan, Yang Xiuquan, Zhang Jun, Bai Liang, Wu Zhiyu. Synthesis and properties of alkyl polyglucoside sulfosuccinate salts with different degrees of esterification[J].China Surfactant Detergent & Cosmetics, 2023, 53(7): 765-772.

Figures/Tables 9

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References 18

[1]	Yang Xiuquan, Zhang Jun, Zhou Yuan, et al. Technological progress of alkyl polyglycosides and its derivatives[J]. China Surfactant Detergent & Cosmetics, 2012, 42 (3) : 213-219.
[2]	Lian Runping. Mildness of sulfosuccinate and its application in cosmetics[J]. China Surfactant Detergent & Cosmetics, 1991 (5) : 34-38.
[3]	Gao Yuyang, Yang Xiuquan, Bai Liang, et al. Preparation and physiochemical properties of disodium lauryl glucosides sulfosuccinate[J]. Journal of Surfactant Detergents, 2014, 17: 603-608. doi: 10.1007/s11743-013-1561-2
[4]	Zhou Yuan, Yang Xiuquan, Zhang Jun. The compounding performance and phase behavior of alkyl Polyglycoside sulfosuccinates and alkyl polyglycoside[J]. Journal of Surfactant and Detergents, 2020, 23: 213-219.
[5]	Zhao Qiuping, Wang Qingning, Zhang Feilong, et al. Study on preparation and property of surfactant alkyl polyglycosides disodoum sulfosuccinate monoester[J]. Chemical Technology, 2010, 18 (1) : 16-19.
[6]	Gao Yuyang, Yang Xiuquan. Equilibrium and dynamic surface properties of sulfosuccinate surfactants[J]. Journal of Surfactant and Detergents, 2014, 17: 1117-1123. doi: 10.1007/s11743-014-1612-3
[7]	Liu Huadao, Zhu Jianhua. Progression synthesis of zeolite molecular sieve membrane[J]. Chemical Industry, 2001, 29 (6) : 16-26.
[8]	Zhou Yuan, Yang Xiuquan, Zhang Jun. Performance and phase behavior of the mixture of alkyl polyglycoside sulfosuccinate and alkyl polyglycoside[J]. China Surfactant Detergent & Cosmetics, 2020, 50 (1) : 20-25.
[9]	Yang Xiuquan, Bai Liang, Zhang Jun, et al. Preparation of glycoside sulfosuccinate by solvent-free method: CN101885745 A[P]. 2010-11-17.
[10]	Zhou Yuan, Yang Xiuquan, Zhang Jun. Effects of head groups on the aggregation behavior of lauryl monoglucoside sulfosuccinates in aqueous solution[J]. Journal of Surfactant and Detergents, 2020, 23: 177-186. doi: 10.1002/jsde.v23.1
[11]	Bai Liang, Yang Xiuquan, Wu Zhiyu. Study of physical and chemical properties of alkyl polyxylosidase[J]. China Surfactant Detergent & Cosmetics, 2018, 48 (11) : 622-626.
[12]	Zhang Xiaolan, Zhou Yuan, Yang Xiuquan. Physicochemical properties of alcohol polyoxyethylene ether acetate/alkyl ethoxy polyglycoside surfactant mixtures[J]. Journal of Dispersion Science and Technology, 2017, 38 (9) : 1252-1257. doi: 10.1080/01932691.2016.1230865
[13]	Han Zhiguo, Yang Xiuquan, Liu Yong, et al. Physicochemical properties and phase behavior of didecyldimethylammonium chloride/alkyl polyglycoside surfactant mixtures[J]. Journal of Surfactant and Detergents, 2015, 18: 641-649. doi: 10.1007/s11743-015-1679-5
[14]	Wang Mengfei, Du Lianzhi, Xu Jianghui, et al. Study on the synthesis of 2-heptyl chloroacetate from methyl chloroacetate by using ionic liquid as a catalysts[J]. China Surfactant Detergent & Cosmetics, 2022, 52 (6) : 601-605.
[15]	Zhang Xiaolan, Zhou Yuan, Yang Xiuquan. Physicochemical properties of alcohol polyoxyethylene ether acetate/alkyl ethoxy polyglycoside surfactant mixtures[J]. Journal of Dispersion Science and Technology, 2017, 38 (9) : 1252-1257. doi: 10.1080/01932691.2016.1230865
[16]	Qin Ziyu, Zhang Jun, Zhou Yuan, et al. Study on the properties of sodium lauroyl lactate anionic surfactant and cationic surfactant in a mixed system[J]. Journal of Molecular Liquids, 2022, 352 (15) : 118544.
[17]	Farajzadeh R, Krastev R, Zitha Pacelli L J. Foam film permeability: Theory and experiment[J]. Advances in Colloid and Interface Science, 2008, 137: 21-44.
[18]	Gong Jiayi, Qiao Jianjiang. Research on the influence of surfactant on foaming and wetting performance[J]. China Surfactant Detergent & Cosmetics, 2012, 51 (11) : 1073-1079.

产品名称	n_APG∶n_顺酐	温度/℃	收率/%
APGSS-M	1∶1.05	90	97.8
APGSS-D	1∶2.1	110	95.3
APGSS-Tr	1∶3.1	120	92.6
APGSS-Te	1∶4.1	140	91.1

Synthesis and properties of alkyl polyglucoside sulfosuccinate salts with different degrees of esterification

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