表面活性剂在活化氧漂体系去除纺织品有色污渍中的作用

doi:10.3969/j.issn.2097-2806.2023.05.003

Abstract

Abstract:

Textiles are often contaminated by coloring matters in daily use. It is difficult to remove these colored stains by using traditional household washing detergents. Peroxides can be used as bleaching agents to remove these colored stains from textiles, however, at relatively high temperatures. Activated peroxide systems are established by adding so-called bleach activators that can react with hydrogen peroxide released from peroxides to generate more kinetically active bleaching species that can break down colored stains at lower temperatures. In this paper, N-[4-（triethylammoniomethyl）benzoyl]caprolactam chloride （TBCC） and tetraacetylethylenediamine （TAED） were used as bleach activators to establish activated peroxide systems in which sodium dodecylbenzenesulfonate （SDBS） and stearyltrimethylammoium chloride （STAC） were added. The formula was designed, aiming to remove colored stains from textiles at room temperature. Morin and coffee were used to simulate the colored stains on textiles. In near-neutral conditions at room temperature, it was found that surfactants themselves could not remove colored stains from textiles, but the ionic charges on these surfactants could interact with the activated peroxide systems and affect their performance on removing colored stains. The formula of activated peroxide system based on TBCC and SDBS was able to effectively remove colored stains from textiles at room temperature. This study might contribute to developing effective household washing formulations for cleaning textiles stained with colored substances.

Key words: bleach activator, surfactant, activated peroxide system, textile, colored stain, cleaning

CLC Number:

TQ423

Fu Jiangpeng, Du Jinmei, Miao Dagang, Xiao Guowei, Jiang Yang, Xu Changhai. Effects of surfactants on removing colored stains from textiles when using activated peroxide systems[J].China Surfactant Detergent & Cosmetics, 2023, 53(5): 511-516.

Figures/Tables 5

Tab. 1

Tab. 2

Tab. 3

Fig. 1

Fig. 2

References 17

[1]	Guo Y N, Shao D Y, Chai W L, et al. Performance of TBCC-activated peroxide systems in removing colored contaminants from textiles[J]. China Surfactant Detergent & Cosmetics, 2018, 48(4): 201-204.
[2]	Chai C X, Zhao L, Zhou Y W, et al. Performance and application of surfactants (ⅩⅧ): Application of surfactants in household detergents[J]. China Surfactant Detergent & Cosmetics, 2015, 45(6): 311-314, 327.
[3]	Odabasi M. Halogenated volatile organic compounds from the use of chlorine-bleach-containing household products[J]. Environmental Science & Technology, 2008, 42(5): 1445-1451. doi: 10.1021/es702355u
[4]	Leri A C, Anthony L N. Formation of organochlorine by-products in bleached laundry[J]. Chemosphere, 2013, 90(6): 2041-2049. doi: 10.1016/j.chemosphere.2012.10.088 pmid: 23261123
[5]	Milne N J. Oxygen bleaching systems in domestic laundry[J]. Journal of Surfactants and Detergents, 1998, 1(2): 253-261. doi: 10.1007/s11743-998-0029-z
[6]	Carson P A, Fairclough C S, Mauduit C, et al. Peroxy bleaches Part 1. Background and techniques for hazard evaluation[J]. Journal of Hazardous Materials, 2006, 136(3): 438-445. pmid: 16513259
[7]	Bianchetti G O, Devlin C L, Seddon K R. Bleaching systems in domestic laundry detergents: a review[J]. RSC Advances, 2015, 5(80): 65365-65384. doi: 10.1039/C5RA05328E
[8]	Hofmann J, Just G, Pritzkow W, et al. Bleaching activators and the mechanism of bleaching activation[J]. Journal Für Praktische Chemie, 1992, 334(4): 293-297. doi: 10.1002/(ISSN)1521-3897
[9]	Li L, Xu Y M, Lu L X, et al. Effect of stabilizer on bleaching activation system of sodium per-carbonate in laundry detergent[J]. China Surfactant Detergent & Cosmetics, 2015, 45(7): 385-388.
[10]	Wang X Y, Du J M, Xu C H. Reactions in activated peroxide systems and their influences on bleaching performance[J]. Mini-reviews in Organic Chemistry, 2021, 18(7): 836-840. doi: 10.2174/1570193X17999201029191747
[11]	Cai J Y, Evans D J, Smith S M. Bleaching of natural fibers with TAED and NOBS activated peroxide systems[J]. AATCC Reviews, 2001, 1(12): 31-34.
[12]	Shao D Y, Chai W L, Du J M, et al. Performance of activated peroxide system based on N-[4- (triethylammoniomethyl) benzoyl]caprolactam chloride in room-temperature cleaning of colored contaminants on textiles[J]. China Surfactant Detergent & Cosmetics, 2019, 49(4): 224-228.
[13]	Cui S S, Zhan Y, Gao J Y, et al. Synthesis of peroxide activator for low-temperature bleaching of cotton fabric[J]. Journal of Textile Research, 2016, 37(7): 88-92.
[14]	Shao D Y, Liu G S, Chen H. Combination of surfactant action with peroxide activation for room-temperature cleaning of textiles[J]. Journal of Surfactants and Detergents, 2021, 24(2): 357-364. doi: 10.1002/jsde.v24.2
[15]	Brooks R E, Moore S B. Alkaline hydrogen peroxide bleaching of cellulose[J]. Cellulose, 2000, 7(3): 263-286. doi: 10.1023/A:1009273701191
[16]	Long X X, Xu C H, Du J M, et al. The TAED/H₂O₂/NaHCO₃ system as an approach to low-temperature and near-neutral pH bleaching of cotton[J]. Carbohydrate Polymers, 2013, 95(1): 107-113. doi: 10.1016/j.carbpol.2013.02.061
[17]	Wang M Z, Long X X, Du J M, et al. X-ray photoelectron spectroscopy analysis of cotton treated with the TBCC/H₂O₂/NaHCO₃ system[J]. Textile Research Journal, 2014, 84(20): 2149-2156. doi: 10.1177/0040517514538694

洗涤配方	ρ/（g/L）
洗涤配方	NaHCO₃	30% H₂O₂	DM1403	TBCC	TAED	SDBS	STAC
1	0	0	0	0	0	0	0
2	0	0	0	0	0	0.50	0
3	0	0	0	0	0	0	0.50
4	1.76	2.04	0.50	0	0	0	0
5	1.76	2.04	0.50	5.50	0	0.00	0
6	1.76	2.04	0.50	5.50	0	0.50	0
7	1.76	2.04	0.50	5.50	0	0	0.50
8	1.76	2.04	0.50	0	1.71	0	0
9	1.76	2.04	0.50	0	1.71	0.50	0
10	1.76	2.04	0.50	0	1.71	0	0.50

纺织品	颜色				WI
纺织品	L^*	a^*	b^*	ΔE	WI
标准样	95.83	0.15	2.82	0.02	76.91
桑色素污渍	89.57	0.30	9.76	8.92	28.87
咖啡污渍	85.70	1.59	11.60	11.63	10.22

样品序号	纺织品污渍	洗涤配方	颜色特征值			WI
样品序号	纺织品污渍	洗涤配方	L^*	a^*	b^*	WI
1	桑色素	1	90.62	-0.06	9.24	33.96
2	桑色素	2	90.97	-0.31	9.55	33.40
3	桑色素	3	89.77	0.27	9.16	32.23
4	桑色素	4	91.29	-0.08	9.23	35.80
5	桑色素	5	95.37	-0.47	4.74	67.03
6	桑色素	6	95.41	-0.45	4.61	67.75
7	桑色素	7	94.62	-0.02	5.43	62.00
8	桑色素	8	93.88	-0.38	6.60	54.71
9	桑色素	9	94.01	-0.48	6.48	55.57
10	桑色素	10	94.86	-0.17	5.12	64.00
11	咖啡	1	85.92	1.37	11.23	12.56
12	咖啡	2	86.53	1.38	10.81	16.16
13	咖啡	3	85.54	1.86	11.44	10.64
14	咖啡	4	87.29	1.35	10.43	19.95
15	咖啡	5	94.83	-0.07	6.66	56.94
16	咖啡	6	94.95	0.05	6.14	59.62
17	咖啡	7	93.19	0.54	8.61	43.72
18	咖啡	8	91.98	0.93	8.79	39.74
19	咖啡	9	92.19	0.87	8.73	40.62
20	咖啡	10	92.89	0.56	8.92	41.53

Effects of surfactants on removing colored stains from textiles when using activated peroxide systems

RichHTML

PDF (PC)

Like

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 5

References 17

Related Articles 15

Metrics

Comments

Recommended 10

[1]	Zhisheng Zhang, Chanliang Shen, Jianxun Li, Yanqiang Liu, Weiwei Han, Sanbao Dong. Preparation and performance of betaine/AOS/Gemini ternary surfactant foam for gas well deliquification [J]. China Surfactant Detergent & Cosmetics, 2024, 54(3): 239-249.
[2]	Guofeng Li, Kainan Liu, Wenlong Mo, Teng Ma. Performance evaluation of a system of imbibition oil displacement agent in shale reservoir [J]. China Surfactant Detergent & Cosmetics, 2024, 54(3): 250-258.
[3]	Hongmei Zhang, Yongmin Zhang. Synthesis and properties of a choline-fatty-acid-based ionic liquid surfactant [J]. China Surfactant Detergent & Cosmetics, 2024, 54(2): 149-155.
[4]	Pei Liu, Ting Pan, Xiaomei Pei, Binglei Song, Jianzhong Jiang, Zhenggang Cui, Bernard P. Binks. Dual-responsive oil-in-water emulsions co-stabilized by a nonionic-anionic Bola surfactant and silica nanoparticles [J]. China Surfactant Detergent & Cosmetics, 2024, 54(1): 1-15.
[5]	Haokang Ai, Yajie Jiang, Yakui Wang, Lu Zhang, Tao Geng. Synthesis and properties of Gemini quaternary ammonium surfactant based on stearate [J]. China Surfactant Detergent & Cosmetics, 2024, 54(1): 16-23.
[6]	Wanping Zhang, Yanzhong Lin, Qianjie Zhang, Dongmei Zhang, Wen Jiang. Study on the phase behavior of sodium lauroyl methyltaurate mediated by Ca²⁺ [J]. China Surfactant Detergent & Cosmetics, 2024, 54(1): 32-37.
[7]	Chang Shiteng, Cai Xiaojun, Zheng Yancheng, Liu Xuejin, Yi Xiao, Jiang Zhuyang. Physicochemical properties of ethoxylated sulfosuccinate surfactants and their interfacial properties when mixed with a betaine surfactant [J]. China Surfactant Detergent & Cosmetics, 2023, 53(9): 989-998.
[8]	Xu Derong,Lian Wei,Xiong Jinzhao,Kang Wanli. Research on the influence factors of surfactant imbibition in tight reservoirs [J]. China Surfactant Detergent & Cosmetics, 2023, 53(8): 857-864.
[9]	Niu Qiqi,Lv Qichao,Dong Zhaoxia,Zhang Fengfan,Wang Hongbo. Research progress on the properties of foam systems containing wormlike micelles [J]. China Surfactant Detergent & Cosmetics, 2023, 53(8): 915-924.
[10]	Wang Jiarui,Wei Xiaocheng,Zhang Chunxue,Chen Peizhen,Zheng Xiangqun,Wang Qiang. Research progress on detection methods of surfactants in water samples from environment [J]. China Surfactant Detergent & Cosmetics, 2023, 53(8): 925-934.
[11]	Qiang Xuefeng, Zhang Li, Zheng Bin, Hou Qianqian, Yan Kun. Study on the inf luence of KCl on the evolution of foam of an anionic surfactant [J]. China Surfactant Detergent & Cosmetics, 2023, 53(7): 733-741.
[12]	Xing Huanyu, Jia Lihua, Zhao Zhenlong, Yang Rui, Guo Xiangfeng. Synthesis and properties of novel surfactants containing naphthalimide and alkyl segments [J]. China Surfactant Detergent & Cosmetics, 2023, 53(7): 742-747.
[13]	Hao Lincong, Xia Xin. Research progress on lavender essential oil microcapsules and application in textiles [J]. China Surfactant Detergent & Cosmetics, 2023, 53(4): 453-458.
[14]	Yongkang Zhang, Mengmeng Liu, Zhiwei Wan, Yaocong Wang, Mimi Tian, Liewei Qiu. Effect of spacer on the performance of Gemini betaine surfactant in clean fracturing fluid [J]. China Surfactant Detergent & Cosmetics, 2023, 53(12): 1398-1404.
[15]	Ting Pan, Junhui Wu, Xiaomei Pei, Zhenggang Cui. Temperature and pH responsive behavior of wormlike micelles formed by novel pseudo-gemini surfactant [J]. China Surfactant Detergent & Cosmetics, 2023, 53(12): 1361-1368.