不同反离子双癸基季铵盐对聚四氟乙烯表面的吸附行为

doi:10.3969/j.issn.1001-1803.2021.08.005

Abstract

Abstract:

The sessile drop method was used to study the adsorption behaviors of a series of didecyl quaternary ammonium salts with different counterions and a Gemini quaternary ammonium salt on the surface of superhydrophobic material polytetrafluoroethylene （PTFE）. The effects of the surface activity, type and concentration of surfactants on the contact angle were investigated, and the changes of spreading coefficient, adhesion tension and adhesion work were discussed. The results show that the contact angle of didecyl quaternary ammonium salts on the surface of PTFE shows a trend of first decreasing and then increasing with the increase of size of counterions. Among them, didecyldimethylammonium valerate （DDAV） which has the largest counterion shows the best wetting on the surface of PTFE; the spreading coefficient （S） is decreased first and then increased with the increase of counterion size; when the concentration of the surfactant is lower than cmc, there is a good linear relationship between adhesion and surface tension; when the concentration is larger than the cmc, the solution of the surfactant with small counterion forms a saturated adsorption layer at the solid-liquid interface and the gas-liquid interface. Surfactants with larger counterions reach saturation adsorption at the gas-liquid interface, but do not reach saturation at the solid-liquid interface. Their adsorption continues and the wetting performance is enhanced with the increase of concentration. Therefore, the influences of a series of didecyl quaternary ammonium salts on the surface of PTFE were obtained, and the adsorption model was established, which provided a theoretical basis for further understanding of the adsorption of such surfactants on the surface of hydrophobic materials, and facilitated the application of such surfactants.

Key words: quaternary ammonium salt, surfactant, adsorption, wetting, contact angle

CLC Number:

TQ423

Zhi Lifei,Shi Xiufang,Zhang Erzhuang,Li Xiaoming,Wang Hui,Pan Ruili. Adsorption behaviors of didecyl quaternary ammonium salts with different counterions on polytetrafluoroethylene surface[J].China Surfactant Detergent & Cosmetics, 2021, 51(8): 725-733.

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References 21

[1]	Zhi Lifei, Li Xiaoming, Wang Hui, et al. Dynamic surface properties of eco-friendly cationic saccharide surfactants at the water/air interface[J]. Tenside. Surf. Det., 2019, 56(6) : 473-482. doi: 10.3139/113.110650
[2]	Qian Feng, Zhou Hongyong, Wang Jiaxi. Syntheses of naphthyl-based quaternary ammonium surfactants and their catalytic properties in chloromethylation of naphthalene[J]. Journal of Molecular Liquids, 2020, 303(1) : 112557-112568. doi: 10.1016/j.molliq.2020.112557
[3]	Cheng Yifan, Chen Hanyu, Basurto L, et al. Inactivation of listeria and E. coli by Deep-UV LED: effect of substrate conditions on inactivation kinetics[J]. Scientific Reports, 2020 (10) : 3411-3421.
[4]	Tang Weiyue, Geng Tao, Jiang Yajie, et al. Properties of didecyldimethylammonium formate and sodium fatty alcohol ether carboxylate mixed systems[J]. Journal of Surfactants and Detergents, 2016, 19:399-404. doi: 10.1007/s11743-015-1781-8
[5]	Zhou Chengcheng, Wang Yilin. Structure-activity relationship of cationic surfactants as antimicrobial agents[J]. Current Opinion in Colloid & Interface Science, 2020, 45:28-43. doi: 10.1016/j.cocis.2019.11.009
[6]	Tang Weiyue, Geng Tao, Dong Ziliang, et al. Influence of carbon chain length of counter-ion of didecyldimethylammonium carboxylate on its surface activity and application performance[J]. China Surfactant Detergent & Cosmetics, 2015, 45(7) : 371-374.
[7]	Hu Sunshuang, Zhang Lei, Xu Zhicheng. Effect of benzyl-substituted alkyl betaine on the wettability of a poly(tetrafluoroethylene) surface[J]. Acta Physico-Chimica Sinica, 2015 (10) : 1924-1931.
[8]	Katarzyna S, Anna Z, Joanna K, et al. Correlation between wetting, adhesion and adsorption in the polymer-aqueous solutions of ternary surfactant mixtures-air systems[J]. Applied Surface Science, 2014, 288(1) : 488-496. doi: 10.1016/j.apsusc.2013.10.059
[9]	Guo Xiangfeng, Jia Lihua. Cationic surfactant and application [M]. Beijing: Chemical Industry Press, 2002: 249-319.
[10]	Zhou Hongtao, Xing Hang, Gou Zhiming, et al. Surface activity, wetting and foaming properties of trialkylammonium perfluorooctanoate[J]. China Surfactant Detergent & Cosmetics, 2010, 40(5) : 320-325.
[11]	Szymczyk K, Jańczuk B. Wettability of a polytetrafluoroethylene surface by an aqueous solution of two nonionic surfactant mixtures[J]. Langmuir, 2007, 23:8740-8746. doi: 10.1021/la7008495
[12]	Yuan Fuqing, Liu Dandan, Guo Lanlei, et al. Effect of branched cationic and betaine surfactants on the wettability of a poly(tetrafluoroethylene) surface[J]. Acta Physico-Chimica Sinica, 2015, 31(4) : 715-721. doi: 10.3866/PKU.WHXB201503028
[13]	Bargeman D, Vader F. Effect of surfactants on contact angles at nonpolar solids[J]. Journal of Colloid and Interface Science, 1973, 42(3) : 467-472. doi: 10.1016/0021-9797(73)90031-3
[14]	Lee L H. Relevance of film pressures to interfacial tension, miscibility of liquids and lewis acid-base approach[J]. J. Colloid Interf. Sci., 1999, 214:64-78. doi: 10.1006/jcis.1999.6165
[15]	Ringelmann A, Riedel M, Riederer M, et al. Two sides of a leaf blade: blumeria graminis needs chemical cues in cuticular waxes of lolium perenne for germination and differentiation[J]. Planta, 2009, 230:95-105. doi: 10.1007/s00425-009-0924-4 pmid: 19352695
[16]	Lucassen-Reynders E H. Contact angles and adsorption on solids[J]. The Journal of Physical Chemistry, 1963, 67(5) : 969-972. doi: 10.1021/j100799a005
[17]	Krawczyk J, Szymczyk K, Zdziennicka A, et al. Wettability of polymers by aqueous solution of binary surfactants mixture with regard to adhesion in polymer-solution system I-correlation between the adsorption of surfactants mixture and contact angle[J]. Int. J. Adhes. Adhes., 2013, 45:106-111. doi: 10.1016/j.ijadhadh.2013.05.002
[18]	Szymczyk K, Jańczuk B. The wettability of polytetrafluoroethylene by aqueous solution of cetyltrimethy- lammonium bromide and TritonX-100 mixtures[J]. Journal of Colloid and Interface Science, 2006, 303:319-325. doi: 10.1016/j.jcis.2006.07.058
[19]	Harkot J, Jańczuk B. Adsorption of sodium bis(2-ethylhexyl) sulfosuccinate and wettability in polytetra-fluoroethylene-solution-air system[J]. Applied Surface Science, 2007, 253(17) : 7166-7171. doi: 10.1016/j.apsusc.2007.02.182
[20]	Harkot J, Jańczuk B. The role of adsorption of dodecylethyl dimethylammonium bromide and benzyldimethyl-dodecylammonium bromide surfactants in wetting of polytetrafluoroethylene and poly(methylmethacrylate) surfaces[J]. Applied Surface Science, 2009, 255:3623-3628. doi: 10.1016/j.apsusc.2008.10.007
[21]	Chang Honghong, Cui Yong, Wang Yuan, et al. Wettability and adsorption of PTFE and Paraffin surfaces by aqueous solutions of biquaternary ammonium salt gemini surfactants with hydroxyl[J]. Colloid Surf. A., 2016, 506:416-424. doi: 10.1016/j.colsurfa.2016.07.012

表面活性剂	DDAF	DDAP	DDAB	DDAV	DDAC	DMHAC10	GC-A
cmc/（mg·mL^-1）	0.145 6	0.455 6	0.431 3	0.425 3	0.259 2	0.366 9	0.242 6
γ_cmc/（mN·m^-1）	24.58	29.14	27.32	25.89	25.04	27.03	31.12

表面活性剂	a	b	R
DDAF	-0.798 4	16.344 9	0.997 7
DDAP	-1.122 5	33.678 8	0.970 7
DDAB	-0.875 9	17.899 2	0.983 5
DDAV	-0.915 9	24.838 8	0.968 8
DDAC	-0.718 2	17.584 6	0.952 2
DMHAC10	-0.718 2	17.584 6	0.959 8
GC-A	-0.739 4	14.162 9	0.989 2

Adsorption behaviors of didecyl quaternary ammonium salts with different counterions on polytetrafluoroethylene surface

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