China Surfactant Detergent & Cosmetics ›› 2021, Vol. 51 ›› Issue (2): 89-97.doi: 10.3969/j.issn.1001-1803.2021.02.002
• Lecture of science and technology • Previous Articles Next Articles
CHEN Feng-feng(),TAO Sheng-nan,GONG Sui-jing,ZHANG Sheng-wei,SUN Ya-juan,YANG Cheng,LI Yun-xing(
)
Received:
2020-11-25
Online:
2021-02-22
Published:
2021-02-22
Contact:
Yun-xing LI
E-mail:cff@jiangnan.edu.cn;yunxingli@jiangnan.edu.cn
CLC Number:
CHEN Feng-feng,TAO Sheng-nan,GONG Sui-jing,ZHANG Sheng-wei,SUN Ya-juan,YANG Cheng,LI Yun-xing. Cosmetic emulsions and new technologies of emulsification (I) Fundamental principles of Pickering emulsions and their applications in cosmetics[J].China Surfactant Detergent & Cosmetics, 2021, 51(2): 89-97.
Fig. 3
Photographs and confocal laser scanning microscopy images of Pickering emulsions containing four commercial oils stabilized by two fumed silica particles with different hydrophobicity (KF-955 is cyclopentasiloxane; KF-96A-6A-6cs is dimethicone; IPM is isopropyl myristate; Miglyol 812N is caprylic/capric triglycerides; AEROSIL? R816 and AEROSIL? R974 are commercial fumed silica particles) (adapted from ref. [17])"
Fig. 4
Retention rate of resveratrol and coenzyme Q10 in Pickering emulsions stabilized by different complexed nanoparticles under been heated at 90 ℃ for 60 min (a) and retention rate of coenzyme Q10 in these Pickering emulsions under UV radiation (b). Res represents resveratrol. CoQ10 represents coenzyme Q10. Z-P-PEs represents Pickering emulsion stabilized by complexed nanoparticles composed of zein and propylene glycol alginate. Z-P-R-PEs represents Pickering emulsion stabilized by complexed nanoparticles composed of zein, propylene glycol alginate and rhamnolipid. Z-P-R-res-PEs represents Pickering emulsion stabilized by resveratrol loaded complexed nanoparticles composed of zein, propylene glycol alginate and rhamnolipid (adapted from Ref.[40])"
Fig. 5
The protective effect of Pickering emulsions to bioactive substances: the release of trans-resveratrol in Pickering emulsion and water under different temperatures (reprinted from Ref.[41]) (a); retention rate of β-carotene in Pickering emulsions and bulk oil at 25 ℃ for 27 days (reprinted from Ref.[45]) (b)"
[1] | Chevalier Y, Bolzinger M-A. Emulsions stabilized with solid nanoparticles: Pickering emulsions[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2013,439:23-34. |
[2] | Ramsdem W. Separation of solids in the surface-layers of solutions and ‘suspensions’[J]. Proceedings of the Royal Society of London, 1903,72:156-164. |
[3] | Pickering, Umfreville S. CXCVI.—Emulsions[J]. Journal of the Chemical Society, Transactions, 1907,91:2001-2021. |
[4] |
Yang Y Q, Fang Z W, Chen X, et al. An overview of Pickering emulsions: solid-particle materials, classification, morphology, and applications[J]. Frontiers in Pharmacology, 2017,8:287.
doi: 10.3389/fphar.2017.00287 pmid: 28588490 |
[5] |
Linke C, Drusch S. Pickering emulsions in foods - opportunities and limitations[J]. Critical Reviews in Food Science and Nutrition, 2018,58(12) : 1971-1985.
pmid: 28414514 |
[6] | Xiao J, Li Y Q, Huang Q R. Recent advances on food-grade particles stabilized Pickering emulsions: Fabrication, characterization and research trends[J]. Trends in Food Science and Technology, 2016,55:48-60. |
[7] | Binks B P, Horozov T S. Colloidal particles at liquid interfaces: an introduction [M]. England: Cambridge University Press, 2006: 1-74. |
[8] | Thieme J, Abend S, Lagaly G. Aggregation in Pickering emulsions[J]. Colloid and Polymer Science, 1999,277(2/3) : 257-260. |
[9] | Lu J, Tian X X, Jin Y L, et al. A pH responsive Pickering emulsion stabilized by fibrous palygorskite particles[J]. Applied Clay Science, 2014,102:113-120. |
[10] |
Hunter T N, Pugh R J, Franks G V, et al. The role of particles in stabilising foams and emulsions[J]. Advances in Colloid and Interface Science, 2008,137(2) : 57-81.
pmid: 17904510 |
[11] |
Costa A L R, Gomes A, Cunha R L. One-step ultrasound producing O/W emulsions stabilized by chitosan particles[J]. Food Research International, 2018,107:717-725.
pmid: 29580539 |
[12] |
Lee M N, Chan H K, Mohraz A. Characteristics of Pickering emulsion gels formed by droplet bridging[J]. Langmuir, 2012,28(6) : 3085-3091.
pmid: 22008060 |
[13] |
Wu J, Ma G H. Recent studies of Pickering emulsions: particles make the difference[J]. Small, 2016,12(34) : 4633-4648.
doi: 10.1002/smll.201600877 pmid: 27337222 |
[14] | Binks B P, Lumsdon S O. Pickering emulsions stabilized by monodisperse latex particles: effects of particle size[J]. Langmuir, 2001,17(15) : 4540-4547. |
[15] |
Ge S J, Xiong L, Li M, et al. Characterizations of Pickering emulsions stabilized by starch nanoparticles: influence of starch variety and particle size[J]. Food Chemistry, 2017,234:339-347.
doi: 10.1016/j.foodchem.2017.04.150 pmid: 28551245 |
[16] |
Binks B P, Clint J H. Solid wettability from surface energy components: relevance to Pickering emulsions[J]. Langmuir, 2002,18(4) : 1270-1273.
doi: 10.1021/la011420k |
[17] | Wu F J, Deng J J, Hu L Y, et al. Investigation of the stability in Pickering emulsions preparation with commercial cosmetic ingredients[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2020,602:125082. |
[18] | Wang H Z, Singh V, Behrens S H. Image charge effects on the formation of Pickering emulsions[J]. Journal of Physical Chemistry Letters, 2012,3(20) : 2986-2990. |
[19] |
Nallamilli T, Binks B P, Mani E, et al. Stabilization of Pickering emulsions with oppositely charged latex particles: influence of various parameters and particle arrangement around droplets[J]. Langmuir, 2015,31(41) : 11200-11208.
pmid: 26411316 |
[20] | Pushpam S D C, Basavaraj M G, Mani E. Pickering emulsions stabilized by oppositely charged colloids: stability and pattern formation[J]. Physical Review E, 2015,92(5) : 52314. |
[21] | Nan F F, Wu J, Qi F, et al. Uniform chitosan-coated alginate particles as emulsifiers for preparation of stable Pickering emulsions with stimulus dependence[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2014,456:246-252. |
[22] | Binks B P, Lumsdon S O. Effects of oil type and aqueous phase composition on oil-water mixtures containing particles of intermediate hydrophobicity[J]. Physical Chemistry Chemical Physics, 2000,2(13) : 2959-2967. |
[23] |
Read E S, Fujii S, Amalvy J I, et al. Effect of varying the oil phase on the behavior of pH-responsive latex-based emulsifiers: demulsification versus transitional phase inversion[J]. Langmuir, 2004,20(18) : 7422-7429.
doi: 10.1021/la049431b pmid: 15323485 |
[24] | Dai L, Zhan X Y, Wei Y, et al. Composite zein-propylene glycol alginate particles prepared using solvent evaporation: characterization and application as Pickering emulsion stabilizers[J]. Food Hydrocolloids, 2018,85:281-290. |
[25] | Xiao J, Wang X A, Gonzalez A J P, et al. Kafirin nanoparticles-stabilized Pickering emulsions: microstructure and rheological behavior[J]. Food Hydrocolloids, 2016,54:30-39. |
[26] | Lissant K J, Peace B W, Wu S H, et al. Structure of high-internal-phase-ratio emulsions[J]. Journal of Colloid and Interface Science, 1974,47(2) : 416-423. |
[27] | Wei Z H, Huang Q R. Development of high internal phase Pickering emulsions stabilised by ovotransferrin-gum arabic particles as curcumin delivery vehicles[J]. International Journal of Food Science & Technology, 2020,55(5) : 1891-1899. |
[28] | Tang M Y, Wu T, Xu X Y, et al. Factors that affect the stability, type and morphology of Pickering emulsion stabilized by silver nanoparticles/graphene oxide nanocomposites[J]. Materials Research Bulletin, 2014,60:118-129. |
[29] | de Folter J W J, van Ruijven M W M, Velikov K P. Oil-in-water Pickering emulsions stabilized by colloidal particles from the water-insoluble protein zein[J]. Soft Matter, 2012,8(25) : 6807-6815. |
[30] | Binks B P, Lumsdon S O. Stability of oil-in-water emulsions stabilised by silica particles[J]. Physical Chemistry Chemical Physics, 1999,1(12) : 3007-3016. |
[31] | Ashby N P, Binks B P. Pickering emulsions stabilised by laponite clay particles[J]. Physical Chemistry Chemical Physics, 2000,2(24) : 5640-5646. |
[32] |
Yang F, Liu S Y, Xu J, et al. Pickering emulsions stabilized solely by layered double hydroxides particles: the effect of salt on emulsion formation and stability[J]. Journal of Colloid and Interface Science, 2006,302(1) : 159-169.
pmid: 16842811 |
[33] | Xi Y K, Liu B, Jiang H, et al. Sodium caseinate as a particulate emulsifier for making indefinitely recycled pH-responsive emulsions[J]. Chemical Science, 2020,11(15) : 3797-3803. |
[34] |
Tao S N, Jiang H, Wang R J, et al. Ultra-stable Pickering emulsion stabilized by a natural particle bilayer[J]. Chemical Communications, 2020,56(90) : 14011-14014.
pmid: 33095226 |
[35] | Ali A, Yilmaz EMS. A novel technology for personal care emulsions[J]. SOFW Journal, 2015,141:11-15. |
[36] | Stiller S, Gers-Barlag H, Lergenmueller M, et al. Investigation of the stability in emulsions stabilized with different surface modified titanium dioxides[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2004,232(2/3):261-267. |
[37] | Marto J, Gouveia L F, Chiari B G, et al. The green generation of sunscreens: using coffee industrial sub-products[J]. Industrial Crops and Products, 2016,80:93-100. |
[38] |
Zembyla M, Murray B S, Radford S J, et al. Water-in-oil Pickering emulsions stabilized by an interfacial complex of water-insoluble polyphenol crystals and protein[J]. Journal of Colloid and Interface Science, 2019,548:88-99.
doi: 10.1016/j.jcis.2019.04.010 pmid: 30981966 |
[39] |
Zembyla M, Lazidis A, Murray B S, et al. Water-in-oil Pickering emulsions stabilized by synergistic particle-particle interactions[J]. Langmuir, 2019,35(40) : 13078-13089.
doi: 10.1021/acs.langmuir.9b02026 pmid: 31525933 |
[40] |
Wei Y, Yu Z P, Lin K S, et al. Fabrication, physicochemical stability, and microstructure of coenzyme Q10 Pickering emulsions stabilized by resveratrol-loaded composite nanoparticles[J]. J Agric Food Chem, 2020,68(5) : 1405-1418.
doi: 10.1021/acs.jafc.9b06678 pmid: 31940190 |
[41] | Dai L, Li Y T, Kong F G, et al. Lignin-based nanoparticles stabilized Pickering emulsion for stability improvement and thermal-controlled release of trans-resveratrol[J]. ACS Sustainable Chemistry & Engineering, 2019,7(15) : 13497-13504. |
[42] | Xiao J, Lo C, Huang Q R. Kafirin nanoparticle-stabilized Pickering emulsions as oral delivery vehicles: physicochemical stability and in vitro digestion profile[J]. Journal of Agrcultural and Food Chemistry, 2015,63(47) : 10263-10270. |
[43] | Vian A, Favrod V, Amstad E. Reducing the shell thickness of double emulsions using microfluidics[J]. Microfluidics and Nanofluidics, 2016,20(12) : 159. |
[44] |
Jiang Y, Wang D, Li F, et al. Cinnamon essential oil Pickering emulsion stabilized by zein-pectin composite nanoparticles: characterization, antimicrobial effect and advantages in storage application[J]. International Journal of Biological Macromolecules, 2020,148:1280-1289.
doi: 10.1016/j.ijbiomac.2019.10.103 pmid: 31739045 |
[45] |
Tan H, Zhao L F, Tian S S, et al. Gelatin particle-stabilized high-internal phase emulsions for use in oral delivery systems: protection effect and in vitro digestion study[J]. J Agric Food Chem, 2017,65(4) : 900-907.
doi: 10.1021/acs.jafc.6b04705 pmid: 28064487 |
[46] | Frelichowska J, Bolzinger M A, Valour J P, et al. Pickering W/O emulsions: drug release and topical delivery[J]. International Journal of Pharmaceutics, 2009,368(1/2):7-15. |
[47] | Frelichowska J, Bolzinger M A, Pelletier J, et al. Topical delivery of lipophilic drugs from o/w Pickering emulsions[J]. International Journal Pharmaceutics, 2009,371(1/2):56-63. |
[48] |
Hayden C G J, Roberts M S, Benson H A E. Systemic absorption of sunscreen after topical application[J]. Lancet, 1997,350(9081) : 863-864.
pmid: 9310609 |
[49] | Braisch B, Köhler K, Schuchmann H P, et al. Preparation and flow behaviour of oil-in-water emulsions stabilised by hydrophilic silica particles[J]. Chemical Engineering & Technology, 2009,32(7) : 1107-1112. |
[50] |
Terescenco D, Hucher N, Picard C, et al. Sensory perception of textural properties of cosmetic Pickering emulsions[J]. International Journal of Cosmetic Science, 2020,42(2) : 198-207.
doi: 10.1111/ics.12604 pmid: 31997376 |
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