微乳型果蔬清洗剂去除农药残留的研究

doi:10.3969/j.issn.1001-1803.2019.12.005

Abstract

Abstract:

The removal effect of microemulusion fruit and vegetable detergents on pesticide residue on vegetable surface was studied. The mixed pesticides containing acephate, omethoate, trichlorfon and cyhalothrin were sprayed on the surface of green vegetables. Then, the vegetables were collected on the 3rd, 7th, 14th, and 21th days after spraying, and washed with the microemulsion detergent, commercially available vegetable and fruit detergent for removing pesticide residue and tap water, respectively. The residues of four pesticides in green vegetable samples were determined. The removal effects of the three cleaning agents on different pesticides and pesticides at different harvest time were evaluated. It is found that with the extension of the harvest time of spraying pesticide, the four pesticide residues in green vegetables decreased to varying degrees, but the cleaning efficiency decreased significantly. Microemulsion fruit and vegetable detergent have good removal effect on all of the four pesticides. The average removal rate of four pesticides in vegetables harvested on the 21st day after spraying is 63.90%, while the average removal rate of commercial vegetable and fruit detergent and tap water is only 44.88% and 20.76%, respectively. Owing to highly hydrophobic solubility and penetrability, the microemulsion detergent was suitable for removal of the highly hydrophobic pesticides and those penetrated into the organic outermost cuticle layer. In view of the good solubilization and permeability of the microemulsion fruit and vegetable detergents, it is suitable for the removal of hydrophobic pesticide residues in the surface of vegetables and fruits.

Key words: microemulsion, fruit and vegetable detergent, pesticide residues, surfactant

CLC Number:

TQ423

LIU Dong,ZHANG Yun,SHANG Meng,NI Xin-jiong,CAO Yu-hua. Study on removal of pesticide residues by microemulsion fruit and vegetable detergents[J].China Surfactant Detergent & Cosmetics, 2019, 49(12): 795-800.

Figures/Tables 7

Tab. 1

Fig. 1

Fig. 2

Tab. 2

Fig. 3

Fig. 4

Fig. 5

References 21

[1]	Syed J H, Alamder A, Mohammad A , et al. Pesticide residues in fruits and vegetables from pakistan: a review of the occurrence and associated human health risks[J]. Environmental Science & Pollution Research, 2014,21(23) : 13367. doi: 10.1007/s11356-019-07057-y pmid: 31865590
[2]	Loughlin T M M, Peluso M L, Etchegoyen M A , et al. Pesticide residues in fruits and vegetables of the argentine domestic market: occurrence and quality[J]. Food Control, 2018,93:129-138. doi: 10.1016/j.foodcont.2018.05.041
[3]	Park D W, Kim K G, Choi E A , et al. Pesticide residues in leafy vegetables, stalk and stem vegetables from South Korea: a long-term study on safety and health risk assessment[J]. Food Additives & Contaminants, 2016,33(1) : 105-118. doi: 10.1016/j.scitotenv.2019.136121 pmid: 31865074
[4]	Qu C L, Kuang H, Xu C L , et al. Assessment on degradation effects of bio-enzyme cleaner on organophosphorus pesticides in vegetables and fruits[J]. Journal of Anhui Agricultural Sciences, 2011,39(34) : 21065-21066.
[5]	Wei F X, Hao L L, Wang J M . Effects of surfactant on environmental pollution and advances in research on its determination[J]. Hebei Journal of Industrial Science & Technology, 2006,23(1) : 57-60. doi: 10.3390/nano10010006 pmid: 31861299
[6]	Dirilgen N, Ince N . Inhibition effect of the anionic surfactant SDS on duckweed, LEMNA minor with considerations of growth and accumulation[J]. Chemosphere, 1995,31(9) : 4185-4196. doi: 10.1016/0045-6535(95)80017-F
[7]	Yan C . Method for preparing sensitive skin special enzyme fruit and vegetable detergent: CN201710162471.6[P]. 2017-07-11.
[8]	Xu X F . High-efficiency antibacterial removal pesticide fruit and vegetable detergent and preparation method: CN201710427037.6[P]. 2017-08-11.
[9]	Mao X B, Du Z P, Tai X M , et al. Progress in research work field with respect to theory and application of microemulsion[J]. China Surfactant Detergent & Cosmetics, 2016,46(11) : 648-653. doi: 10.1016/j.chemosphere.2019.125559 pmid: 31841794
[10]	Qiu B Y . Emulsification and its applications in cosmetic industry(Ⅳ): microemulsions and multiple emulsions[J]. China Surfactant Detergent & Cosmetics, 1999(6) : 50-56. doi: 10.1016/j.chemosphere.2019.125559 pmid: 31841794
[11]	Du Z P, Mao X B, Tai X M , et al. Preparation and properties of microemulsion detergent with linear medium chain fatty alcohols as oil phase[J]. Journal of Molecular Liquids, 2016,223:805-810. doi: 10.1016/j.molliq.2016.09.011
[12]	Cai Z S . Study and preparation of microemulsion-type detergent for kitchen[J]. China Surfactant Detergent & Cosmetics, 2002,32(3) : 75-77. doi: 10.1016/j.chemosphere.2019.125559 pmid: 31841794
[13]	Yi F P, Yao Y, Zhang L R . Study on preparation and properties of lemon oil micro-emulsion system[J]. Chemical World, 2016,57(12) : 771-778.
[14]	Zhang L J, Liu S W, Cui X Y . A review of sample preparation methods for the pesticide residue analysis in foods[J]. Central European Journal of Chemistry, 2012,10(3) : 900-925. doi: 10.2478/s11532-012-0034-1
[15]	Yang H Y, Yu Y, Zheng X L . Application of solid-phase extraction and matrix solid-phase dispersion in orange sample preparation for organophosphorous pesticide residues analysis[J]. Chinese Journal of Chromatography, 2008,26(6) : 744.
[16]	Grimalt S, Dehouck P . Review of analytical methods for the determination of pesticide residues in grapes[J]. Journal of Chromatography A, 2016,1433:1-23. doi: 10.1016/j.chroma.2015.12.076 pmid: 26803907
[17]	Sami B, Olivier P, Marie F , et al. Analysis of pesticide residues in essential oils of citrus fruit by GC-MS and HPLC-MS after solid-phase extractions[J]. Analytical and Bioanalytical Chemistry, 2003,376(2) : 157-161. doi: 10.1007/s00216-003-1899-9 pmid: 12712311
[18]	Machado I, Gerez N, Piston M , et al. Determination of pesticide residues in globe artichoke leaves and fruits by GC-MS and LC-MS/MS using the same QuEChERS procedure[J]. Food Chemistry, 2017,227:227-236. doi: 10.1016/j.foodchem.2017.01.025 pmid: 28274427
[19]	Liu M, Xie Y, Li H C . et al. Multiresidue determination of 29 pesticide residues in pepper through a modified QuEChERS method and gas chromatography-mass spectrometry[J]. Biomedical Chromatography Bmc, 2016,30(10) : 1686-1695. doi: 10.1002/bmc.3742 pmid: 27076195
[20]	Tripathy V, Saha V, Kumar V , et al. Detection of pesticides in popular medicinal herbs: a modified QuEChERS and gas chromatography-mass spectrometry based approach[J]. Journal of Food Science & Technology, 2017,54(2) : 1-11. doi: 10.1111/1750-3841.14952 pmid: 31856339
[21]	Liu D, Zhang Y, Wang G X . A preparation method of microemulsion type vegetable and fruit detergents for removing pesticide residues: CN201810792733.1[P]. 2018-11-23.

农药化合物	保留时间/min	定量离子m/z	定性离子m/z
乙酰甲胺磷	7.591	136	136、94、42
氧乐果	10.582	110	110、156、79
敌百虫	12.427	109	109、79、185
氯氟氰菊酯	21.866	181	181、197、208

农药化合物	线性方程	相关系数R²	线性范围/（mg·L^-1）	检出限/（mg·kg^-1）	定量限/（mg·kg^-1）
乙酰甲胺磷	A =1.22×10⁵ρ-1.44×10⁵	0.997	2.0~100	0.000 4	0.001 3
氧乐果	A =2.30×10⁵ρ-6.28×10⁵	0.992	5.0~100	0.000 6	0.002 0
敌百虫	A =7.46×10⁴ρ + 4.43×10³	1.000	0.2~100	0.000 4	0.001 3
氯氟氰菊酯	A =1.56×10⁵ρ-2.45×10⁴	0.998	0.2~100	0.004 0	0.013 3

Study on removal of pesticide residues by microemulsion fruit and vegetable detergents

RichHTML

PDF (PC)

Like

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 7

References 21

Related Articles 15

Metrics

Comments

Recommended 10

[1]	Zhisheng Zhang, Chanliang Shen, Jianxun Li, Yanqiang Liu, Weiwei Han, Sanbao Dong. Preparation and performance of betaine/AOS/Gemini ternary surfactant foam for gas well deliquification [J]. China Surfactant Detergent & Cosmetics, 2024, 54(3): 239-249.
[2]	Guofeng Li, Kainan Liu, Wenlong Mo, Teng Ma. Performance evaluation of a system of imbibition oil displacement agent in shale reservoir [J]. China Surfactant Detergent & Cosmetics, 2024, 54(3): 250-258.
[3]	Kangfu Zhou, Yixuan Zhi, Feifei Wang, Yazhuo Shang. New emulsion system and its application in cosmetics （VI）Microemulsion [J]. China Surfactant Detergent & Cosmetics, 2024, 54(2): 139-148.
[4]	Hongmei Zhang, Yongmin Zhang. Synthesis and properties of a choline-fatty-acid-based ionic liquid surfactant [J]. China Surfactant Detergent & Cosmetics, 2024, 54(2): 149-155.
[5]	Pei Liu, Ting Pan, Xiaomei Pei, Binglei Song, Jianzhong Jiang, Zhenggang Cui, Bernard P. Binks. Dual-responsive oil-in-water emulsions co-stabilized by a nonionic-anionic Bola surfactant and silica nanoparticles [J]. China Surfactant Detergent & Cosmetics, 2024, 54(1): 1-15.
[6]	Haokang Ai, Yajie Jiang, Yakui Wang, Lu Zhang, Tao Geng. Synthesis and properties of Gemini quaternary ammonium surfactant based on stearate [J]. China Surfactant Detergent & Cosmetics, 2024, 54(1): 16-23.
[7]	Wanping Zhang, Yanzhong Lin, Qianjie Zhang, Dongmei Zhang, Wen Jiang. Study on the phase behavior of sodium lauroyl methyltaurate mediated by Ca²⁺ [J]. China Surfactant Detergent & Cosmetics, 2024, 54(1): 32-37.
[8]	Chang Shiteng, Cai Xiaojun, Zheng Yancheng, Liu Xuejin, Yi Xiao, Jiang Zhuyang. Physicochemical properties of ethoxylated sulfosuccinate surfactants and their interfacial properties when mixed with a betaine surfactant [J]. China Surfactant Detergent & Cosmetics, 2023, 53(9): 989-998.
[9]	Xu Derong,Lian Wei,Xiong Jinzhao,Kang Wanli. Research on the influence factors of surfactant imbibition in tight reservoirs [J]. China Surfactant Detergent & Cosmetics, 2023, 53(8): 857-864.
[10]	Niu Qiqi,Lv Qichao,Dong Zhaoxia,Zhang Fengfan,Wang Hongbo. Research progress on the properties of foam systems containing wormlike micelles [J]. China Surfactant Detergent & Cosmetics, 2023, 53(8): 915-924.
[11]	Wang Jiarui,Wei Xiaocheng,Zhang Chunxue,Chen Peizhen,Zheng Xiangqun,Wang Qiang. Research progress on detection methods of surfactants in water samples from environment [J]. China Surfactant Detergent & Cosmetics, 2023, 53(8): 925-934.
[12]	Qiang Xuefeng, Zhang Li, Zheng Bin, Hou Qianqian, Yan Kun. Study on the inf luence of KCl on the evolution of foam of an anionic surfactant [J]. China Surfactant Detergent & Cosmetics, 2023, 53(7): 733-741.
[13]	Xing Huanyu, Jia Lihua, Zhao Zhenlong, Yang Rui, Guo Xiangfeng. Synthesis and properties of novel surfactants containing naphthalimide and alkyl segments [J]. China Surfactant Detergent & Cosmetics, 2023, 53(7): 742-747.
[14]	Fu Jiangpeng, Du Jinmei, Miao Dagang, Xiao Guowei, Jiang Yang, Xu Changhai. Effects of surfactants on removing colored stains from textiles when using activated peroxide systems [J]. China Surfactant Detergent & Cosmetics, 2023, 53(5): 511-516.
[15]	Yongkang Zhang, Mengmeng Liu, Zhiwei Wan, Yaocong Wang, Mimi Tian, Liewei Qiu. Effect of spacer on the performance of Gemini betaine surfactant in clean fracturing fluid [J]. China Surfactant Detergent & Cosmetics, 2023, 53(12): 1398-1404.