添加盐对Gemini阳离子表面活性剂溶液的影响

doi:10.13218/j.cnki.csdc.2016.10.001

Abstract

Abstract: Effect of addition of sodium salicylate (NaSal) on viscoelastic performance of aqueous solution of Gemini cationic surfactant 2-hydroxy propylidene-1,3-bis(dimethyldodecylammonium chloride) (hereinafter refer to as 12-3(OH)-12(2Cl)) was studied with rheological measurement.Results showed that the addition of an inorganic salt induces salting out of the 12-3(OH)-12(2Cl),while NaSal promotes micellar growth.At a fixed NaSal-to-surfactant molar ratio of 0.6,viscosity of the solution is very small at a rather low concentration of 12-3(OH)-12(2Cl).Upon increasing the concentration,viscosity of the solution rises conspicuously and shows Maxwell fluid behavior.Following the increase of concentration of 12-3(OH)-12(2Cl),a maximum value of zero-shear viscosity (η₀) appears.These trends can be attributed to the formation of a network structure between the cationic ions of 12-3(OH)-12(2Cl) and Sal^- counter ion as the 12-3(OH)-12(2Cl) concentration increases.Crystal analysis further confirms the presence of structures linked by intermolecular hydrogen bonds.

Key words: Gemini cationic surfactant, rheological behavior, intermolecular hydrogen bond, wormlike micelle

CLC Number:

TQ423.12

CHEN Xiao-xiao,GUO Yan,HAN Chuan-hong,ZHANG Jun-hong,ZHOU Shi-yan,WEI Xi-lian. Effect of addition of salt on solution of Gemini cationic surfactant[J].China Surfactant Detergent & Cosmetics, 2016, 46(10): 549-554.

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Effect of addition of salt on solution of Gemini cationic surfactant

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