Pickering Janus乳液微观结构的影响因素及其应用

doi:10.3969/j.issn.2097-2806.2025.02.006

Abstract

Abstract:

Janus emulsions stabilized by solid particles as emulsifier can be called Pickering Janus emulsions. Pickering Janus emulsions have double advantages of Pickering emulsions and Janus emulsions. Compared with the traditional emulsions, Janus emulsions have the advantages of stronger separation and better solubilization abilities, and have broad application prospects in the transportation and storage of active substances. Compared with Janus emulsions stabilized by surfactant, Janus emulsions stabilized by solid particles are less toxic, more stable and environmentally friendly. In this paper, Pickering Janus emulsions, in which cellulose nanocrystals （CNCs） was used as emulsifier and silicone oil （O1） and its immiscible oil （O2） were used as oil phases, were prepared by one-step homogenization method. The effects of oil property （O2）, the relative content of O1 to O2, the content of coemulsifier and preparation technology on the topological structure and droplet size of the emulsions were investigated. The results show that Pickering Janus emulsions have highly controllable topology and size. By changing the type of oil （O2）, the emulsion droplets can be changed from a partially engulfed dumbbell Janus structure to a fully engulfed core-shell structure. By adjusting the relative content of O1 to O2, the volume ratio of two phases in the droplet can be precisely controlled. The surface coverage of one phase relative to another can be adjusted by changing the content of coemulsifier. In addition, the size of the emulsion droplets can be controlled by changing the emulsification energy （such as the homogenization rate）. The higher homogenization rate is, the smaller sizes of the droplets are. The release behavior of the active substances in the system can also be adjusted by changing the relative content of two oils or the content of coemulsifier. In addition, Pickering Janus emulsion has a better slow-release effect than traditional Janus emulsion. This study provides guidance for the practical application of the new emulsion system in the field of cosmetics.

Key words: Pickering Janus emulsion, topological structure, solid particle, slow release

CLC Number:

TQ658

Xu Han,Jiajia Wu,Kangfu Zhou,Yazhuo Shang. Influence factors on microstructure of Pickering Janus emulsions and its application[J].China Surfactant Detergent & Cosmetics, 2025, 55(2): 176-184.

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References 37

[1]	Hasinovic H, Friberg S E, Guo Rong. A one-step process to a Janus emulsion[J]. Journal of Colloid and Interface Science, 2011, 354(1): 424-426. doi: 10.1016/j.jcis.2010.10.004 pmid: 20970807
[2]	Kovach I, Won J, Friberg S E, et al. Completely engulfed olive/silicone oil Janus emulsions with gelatin and chitosan[J]. Colloid and Polymer Science, 2016, 294(4): 705-713.
[3]	Zhang Qingquan, Xu Meng, Liu Xiaojun, et al. Fabrication of Janus droplets by evaporation driven liquid-liquid phase separation[J]. Chemical Communications, 2016, 52(28): 5015-5018. doi: 10.1039/c6cc00249h pmid: 26983706
[4]	Zhang Qifan, Savagatrup S, Kaplonek P, et al. Janus emulsions for the detection of bacteria[J]. ACS Central Science, 2017, 3(4): 309-313. doi: 10.1021/acscentsci.7b00021 pmid: 28470048
[5]	Raju R R, Liebig F, Hess A, et al. Temperature-triggered reversible breakdown of polymer-stabilized olive-silicone oil Janus emulsions[J]. RCS Advance, 2019, 9(34): 19271-19277.
[6]	Ge Lingling, Li Jingjing, Cheng Jingru, et al. A method for preparing nano Janus emulsion by low energy method: CN105778119A[P]. 2016-07-20.
[7]	李侠. 反相Janus乳液的制备及稳定性研究[D]. 扬州: 扬州大学, 2018.
[8]	Guzowski J, Korczyk P M, Jakiela S, et al. The structure and stability of multiple micro-droplets[J]. Soft Matter, 2012, 8(27): 7269-7278.
[9]	Hasinovic H, Friberg S E. One-step inversion process to a Janus emulsion with two mutually insoluble oils[J]. Langmuir, 2011, 27(11): 6584-6588. doi: 10.1021/la105118h pmid: 21534548
[10]	Kovach I, Koetz J, Friberg S E. Janus emulsions stabilized by phospholipids[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2014, 441(20): 66-71.
[11]	Ge Lingling, Lu Shuhui, Han Jie, et al. Anisotropic particles templated by Janus emulsion[J]. Chemical Communication, 2015, 51(35): 7407-7566.
[12]	Ramsden W. Separation of solids in the surface-layers of solutions and suspensions (observations on surface membranes, bubbles, emulsions, and mechanical coagulation): preliminary account[J]. Proceedings of the Royal Society of London, 1903, 72(4): 156-164.
[13]	Pickering S U. CXCVI: Emulsions[J]. Journal of the Chemical Society, 1907, 91: 2001-2021.
[14]	Binks B P. Particles as surfactants—similarities and differences[J]. Current Opinion in Colloid & Interface Science, 2002, 7(1/2): 21-41.
[15]	Leal-Calderon F, Schmitt V. Solid-stabilization emulsions[J]. Current Opinion in Colloid & Interface Science, 2008, 13(4): 217-227.
[16]	Alison L, Rühs P A, Tervoort E, et al. Pickering and network stabilization of biocompatible emulsions using chitosan-modified silica nanoparticles[J]. Langmuir, 2016, 32(50): 13446-13457. pmid: 27935304
[17]	Tang Juntao, Quinlan P J, Tam K C. Stimuli-responsive Pickering emulsions: recent advances and potential applications[J]. Soft Matter, 2015, 11: 3512-3529. doi: 10.1039/c5sm00247h pmid: 25864383
[18]	Wu Jie, Ma Guanghui. Recent studies of Pickering emulsions: particles make the difference[J]. Small, 2016, 12(34): 4633-4648. doi: 10.1002/smll.201600877 pmid: 27337222
[19]	Zhang Qianjie, Shen Xingliang, Zhang Dongmei, et al. Fabrication and characterization of novel high internal Pickering emulsions stabilized solely by ultrafine pearl powder[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2021, 624: 126797.
[20]	Marto J, Gouveia L F, Goncalves L, et al. Design of novel starch-based Pickering emulsions as platforms for skin photoprotection[J]. Journal of Photochemistry and Photobiology, B: Biology, 2016, 162: 56-64.
[21]	Jia Bing, Zhang Zheng, Chen Minghua, et al. Effect of liquid oils on the properties of multiple emulsions containing liquid crystals[J]. Journal of Dispersion Science Technology, 2017, 38(6): 876-882.
[22]	El-Mahrab-Robert M, Rosilio V, Bolzinger M A, et al. Assessment of oil polarity: comparison of evaluation methods[J]. International Journal of Pharmaceutics, 2008, 348(1/2): 89-94.
[23]	韩旭, 吴槚佳, 吴娜. 新型乳化体系及其在化妆品中的应用(V): Janus乳液[J]. 日用化学工业, 2014, 54(1): 24-31.
[24]	Zarzar L, Sresht V, Sletten E, et al. Dynamically reconfigurable complex emulsions via tunable interfacial tensions[J]. Nature, 2015, 518(7540): 520-524.
[25]	Ge Lingling, Shao Wangqing, Lu Shuhui, et al. Droplet topology control of Janus emulsion prepared in one-step high energy mixing[J]. Soft Matter, 2014, 10: 4498-4505. doi: 10.1039/c4sm00456f pmid: 24806329
[26]	Friberg S E, Kovach I, Koetz J. Equilibrium topology and partial inversion of Janus drops: A numerical analysis[J]. ChemPhysChem, 2013, 14(16): 3772-3776. doi: 10.1002/cphc.201300635 pmid: 24105990
[27]	Friberg S E. Equilibrium Janus drop topology. 2. A single drop in a spherical continuous phase[J]. Journal of Dispersion Science and Technology, 2015, 36(12): 1685-1692.
[28]	Leonardi G R, Perrechil F A, Silveira L P, et al. Silicone/vegetable oil Janus emulsion: topological stability versus interfacial tensions and relative oil volumes[J]. Journal of Colloid and Interface Science, 2015, 449: 31-37. doi: 10.1016/j.jcis.2014.09.028 pmid: 25443127
[29]	程静茹. 乳液中的磁性Janus液滴的场控运动及应用研究[D]. 扬州: 扬州大学, 2020.
[30]	Pannacci N, Bruus H, Bartolo D, et al. Equilibrium and nonequilibrium states in microfluidic double emulsions[J]. Physical Review Letters, 2008, 101(16): 164502.
[31]	Dendukuri D, Doyle P S. The synthesis and assembly of polymeric microparticles using microfluidics[J]. Advanced Materials, 2009, 21(41): 4071-4086.
[32]	Nie Zhihong, Xu Shengqing, Seo M, et al. Polymer particles with various shapes and morphologies produced in continuous microfluidic reactors[J]. Journal of the American Chemical Society, 2005, 127(22): 8058-8063. pmid: 15926830
[33]	Ge Lingling, Friberg S E, Guo Rong. Recent studies of Janus emulsions prepared by one-Step vibrational mixing[J]. Current Opinion in Colloid & Interface Science, 2016, 25: 58-66.
[34]	Tadros T F. Emulsion formation, stability, and rheology[J]. Emulsion Formation and Stability, 2013, 16: 1-75.
[35]	Kramer K A, Liebler D C. UVB induced photooxidation of vitamin E[J]. Chemical Research in Toxicology, 1997, 10(2): 219-224. pmid: 9049434
[36]	Krishnamurthy S. The intriguing biological role of vitamin E[J]. Journal of Chemical Education, 1983, 60(6): 465.
[37]	陈秋娣. (FC-770+烷烃)/水体系乳液微反应器的构筑及Michael加成反应的调控[D]. 扬州: 扬州大学, 2023.

原料分组	组分	质量分数/%
水相	水纤维素纳米晶卡波U21	至100.00 0.10 0.18
油相	100粘硅油（O1）油脂（O2）	5.00~15.00 10.00~15.00
油相	卵磷脂类液晶乳化剂维生素E	0~0.35 0~3.00
其他	质量分数为10%的氢氧化钠水溶液	0.36

液-液	界面张力/ （mN/m）	液-液	界面张力/ （mN/m）	液-液	界面张力/ （mN/m）	液-液	界面张力/ （mN/m）
CNCs水分散液-硅油	20.6	CNCs水分散液-硅油	20.6	CNCs水分散液-硅油	20.6	CNCs水分散液-硅油	20.6
CNCs水分散液-橄榄油	15.1	CNCs水分散液-荷荷巴油	17.6	CNCs水分散液-辛酸/癸酸甘油三酯	19.4	CNCs水分散液-角鲨烷	41.4
硅油-橄榄油	5.2	硅油-荷荷巴油	2.5	硅油-辛酸/癸酸甘油三酯	1.1	硅油-角鲨烷	2.4

Influence factors on microstructure of Pickering Janus emulsions and its application

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