益智精油O/W型微乳液的制备及其性能研究

doi:10.3969/j.issn.2097-2806.2024.10.007

Abstract

Abstract:

Alpinia oxyphylla Miq. extract is a kind of natural cosmetic raw material, which can be used as plant functional oil. In order to obtain a stable O/W microemulsion of Alpinia oxyphylla Miq. essential oil（AOEO）, the O/W microemulsion containing AOEO was constructed by pseudo ternary phase diagram method. The effects of surfactants, cosurfactants, K_m （mass ratio of surfactant to cosurfactant）, and their different components and ratios on the area of the microemulsion were investigated. The particle size, morphology, conductivity, water solubility and stability of the microemulsion were measured, and its characterization and physicochemical properties were discussed. The results show that the optimal formula of O/W microemulsion of AOEO is obtained as follows: m（castor oil polyoxyethylene ether 40 （EL-40）） ∶m（1,2-propylene glycol） ∶m（AOEO）=10.5∶3.5∶6, the transition point of O/W microemulsion is 60% （mass fraction）. The average particle size of the O/W microemulsion is （26.580±0.133） nm, the polydispersion index （PDI） is 0.226±0.010, and the microemulsion is slightly spherical or quasi-spherical, regular, and without adhering edges under transmission electron microscopy （TEM） and digital biological microscopy （DBM）. The microemulsion has good water solubility, centrifugal stability, thermal stability and low temperature storage stability. The results show that the nano-coating of AOEO can be realized by using microemulsion as carrier, which provides reference for the development and application of AOEO in daily chemical field.

Key words: Alpinia oxyphylla Miq. essential oil, microemulsion, pseudo ternary phase diagram, castor oil polyoxyethylene ether, O/W

CLC Number:

TQ658

Xiaoli Xie, Xuan Hu, Ying Huang, Kai Wang, Dan Wang, Fulai Yu. Preparation and properties of O/W microemulsion of Alpinia oxyphylla Miq. essential oil[J].China Surfactant Detergent & Cosmetics, 2024, 54(10): 1201-1210.

Figures/Tables 13

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References 27

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表面活性剂	HLB值	乳液外观
司盘80	4.3	分层
吐温80	15	不分层
吐温60	14.5	不分层
吐温20	16.5	分层
OP-10	14.5	不分层
EL-40	13~14	不分层
APG0810	15~16	分层
曲通X-100	14.5	不分层

S_mix	平均粒径/nm	PDI	外观
9∶1	32.87±2.70^c	0.272±0.005^c	澄清透明，久置1年不分层
8∶2	21.17±0.55^a	0.09±0.03^a	澄清透明，久置1年不分层
7∶3	26.580±0.133^ab	0.226±0.010^b	澄清透明，久置1年不分层

离心速率/ （r/min）	益智精油微乳液
离心速率/ （r/min）	透光率%	形态变化
2 000	99.52	黄色澄清透明、无分层或浑浊
4 000	98.86	黄色澄清透明、无分层或浑浊
6 000	97.31	黄色澄清透明、无分层或浑浊
8 000	95.86	黄色澄清透明、无分层或浑浊
10 000	95.17	黄色澄清透明、无分层或浑浊

Preparation and properties of O/W microemulsion of Alpinia oxyphylla Miq. essential oil

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