三七根提取物的表面活性及其复配体系的性能研究

doi:10.3969/j.issn.2097-2806.2024.08.012

Abstract

Abstract:

The surface activity and compound synergy of Panax notoginseng root extract were studied. The results show that the cmc of Panax notoginseng root extract at 25 ℃ is 0.1 g/L and γ_cmc is 43.67 mN/m. In the salinity mass fraction range of 0%-1%, the surface activity increases with the increasing saltness. In the pH between 4.0-8.0, the surface tension of Panax notoginseng root extract decreases with the decreasing pH. According to Rosen’s theory, the optimal compound mass ratio between Panax notoginseng root extract and Tween 20 is 4∶1, and it is found that the ability of the mixed system to form micelles increases by 41.18% compared with the theoretical results. The emulsifying ability results show that the emulsifying ability and emulsifying stability of the mixed system are close to Tween 20 alone, indicating that the combination of Panax notoginseng root extract and Tween 20 has a good synergistic effect, but not on Tween 60.

Key words: natural biosurfactants, saponins, Panax notoginseng root extract, surface activity, synergism

CLC Number:

TQ423

Jitao Liu,Yuxi Wang,Xuanlin Yang. Study on the surface activity of Panax notoginseng root extract and the properties of the mixed system[J].China Surfactant Detergent & Cosmetics, 2024, 54(8): 974-980.

Figures/Tables 10

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References 20

[1]	Podolak I, Galanty A, Sobolewska D. Saponins as cytotoxic agents: a review[J]. Phytochemistry Reviews, 2010, 9 (3) : 425-474. pmid: 20835386
[2]	Vincken J P, Heng L, Aede D G A D G, et al. Saponins, classification and occurrence in the plant kingdom[J]. Phytochemistry, 2007, 68 (3) : 275-297.
[3]	Yang Y, Leser M E, Sher A A, et al. Formation and stability of emulsions using a natural small molecule surfactant: Quillaja saponin (Q-Naturale)[J]. Food Hydrocolloids, 2013, 30 (2) : 589-596.
[4]	Hostettmann K, Marston A. Saponins[M]. Cambridge: Cambridge University Press, 1995 (5) :232-286.
[5]	Güçlü-Üstündağ Ö, Mazza G. Saponins: properties, applications and processing[J]. Critical Reviews in Food Science and Nutrition, 2007, 47 (3) : 231-258. doi: 10.1080/10408390600698197 pmid: 17453922
[6]	Sparg S G, Light M E, Van S J. Biological activities and distribution of plant saponins[J]. Journal of Ethnopharmacology, 2004, 94 (2-3) : 219-243. doi: 10.1016/j.jep.2004.05.016 pmid: 15325725
[7]	Bao Jiancai, Liu Gang, Cong Dengli, et al. Research progress on the chemical composition of Panax notoginseng[J]. Proprietary Chinese Medicines, 2006, 28 (2) : 246-253.
[8]	Long Chaoming. A review of studies on Panax notoginseng[J]. Journal of Practical Chinese Medicine, 2013 (6) : 502-503.
[9]	Ma Jinshuang, Yu Haiying. Medicinal plant resources of the Chinese family Araliaceae[J]. Chinese Herbal Medicine, 1989, 20 (11) : 41-44.
[10]	Gao Siyu, Huo Tong, Li Xuetao, et al. Study on the anti-aging efficacy of Sanqi extract[J]. China Surfactant Detergent & Cosmetics, 2020, 50 (11) : 783-787.
[11]	Wei Junxian, Wang Jufen, Chang Liangyu, et al. Chemical studies of San-Chi Panax notoginseng (Burk.) F. H. Chen. I. Studies on the constituents of San-Chi root hairs[J]. Acta pharmaceutica Sinica, 1980, 15 (6) : 359-364. pmid: 7457155
[12]	Peng Shunjin, Zhang Guijun, Chen Zhengguo, et al. Composition, performance, characterization and application of Span and Tween[J]. Surfactant Industry, 1998 (1) : 12-16.
[13]	Rosen M J, Kunjappu J T. Surfactants and interfacial phenomena[M]. Hoboken: John Wiley & Sons, 2012.
[14]	Xia Chunhua, Zhu Quanfen, Tian Jiehua, et al. Surface activity of tea saponin and the related functional properties[J]. Journal of Tea Science, 1990, 10 (1) : 1-10.
[15]	Schreiner T B, Colucci G, Santamaria-Echart A, et al. Evaluation of saponin-rich extracts as natural alternative emulsifiers: A comparative study with pure Quillaja Bark saponin[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2021, 623: 126748.
[16]	Gui Qing, Zhang Yufeng, Duan Kejun. Surface activities of coconut endocarp oil-xylose ester[J]. China Oils and Fats, 2016, 41 (1) : 72-75.
[17]	Russell L L. Chemical aspects of groundwater recharge with waste waters[M]. Berkeley: University of California, Berkeley, 1976.
[18]	Myers D. Surfaces, interfaces, and colloids: principles and applications[M]. New York: VCH Publishers, 1999.
[19]	Rosen M J, Hua X Y. Surface concentrations and molecular interactions in binary mixtures of surfactants[J]. Journal of Colloid and Interface Science, 1982, 86 (1) : 164-172.
[20]	Wang Zhengwu, Li Ganzuo, Li Ying. Study on surface activity of gleditsin and its mixed system[J]. China Surfactant Detergent & Cosmetics, 2000 (6) : 1-4.

三七根提取物水溶液质量浓度/（g/L）	pH	电导率/（μS/cm）
0.5	6.67	7.14
1.0	6.43	9.36
2.0	6.26	10.26
5.0	6.17	26.30

复配体系及比例	m（三七根提取物）∶m（Tween 20）
复配体系及比例	体系Ⅰ 8∶1	体系Ⅱ 4∶1	体系Ⅲ 1∶1
cmc_理/ （g/L）	0.18	0.08	0.025
γ_cmc理/ （mN/m）	38.10	42.96	48.55
cmc_表/ （g/L）	0.25	0.05	0.05
γ_cmc表/ （mN/m）	33.93	42.45	38.38
A/%	-38.46	41.18	-100.00
B/%	10.94	1.18	20.95

复配体系及比例	m（三七根提取物） ∶ m（Tween 60）=1∶1
cmc_理/ （g/L）	0.10
γ_cmc理/ （mN/m）	42.60
cmc_表/ （g/L）	0.20
γ_cmc表/ （mN/m）	42.82
A/%	-100.00
B/%	-0.52

Study on the surface activity of Panax notoginseng root extract and the properties of the mixed system

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