三甲基硅基普鲁兰多糖的制备与性能

doi:10.3969/j.issn.1001-1803.2020.11.005

Abstract

Abstract:

Trimethylsilyl pullulan was synthesized using N, O-bis（trimethylsilyl）acetamide （BSA） as the silylation agent. The structure of the modified pullulan was characterized by ¹H NMR, FT-IR and XPS. When n（P-OH）:n（BSA） was 9:15, the degree of substitution（DS） was as high as 2.89. Trimethylsilyl pullulan has excellent film-forming properties. The tensile strength and elongation at break of the film decrease with the increase of DS, but this phenomenon disappears when the DS is above 1.55. As the DS increases, the contact angle of the membrane with water and sebum increases, and the hydrophobic film has a certain degree of sebum resistance. Trimethylsilyl pullulan can emulsify the water phase to form a water-in-oil emulsion. The effects of DS and the type of oil phase on emulsification properties were studied. It shows that when the DS is 1.91, the emulsification performance is the best. Compared with the emulsion stabilized by EM90, although the size of emulsion stabilized by trimethylsilyl pullulan is larger, it has higher viscosity and better stability.

Key words: silylation, modified pullulan, film-forming, water-in-oil emulsion, cosmetic additives

CLC Number:

TQ658

JI Ying-ying,YANG Cheng. Preparation and properties of trimethylsilyl pullulan[J].China Surfactant Detergent & Cosmetics, 2020, 50(11): 762-770.

Figures/Tables 14

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References 20

[1]	Sroková I, Tomanová V, Ebringerová A, et al. Water-soluble amphiphilic o-(carboxymethyl) cellulose derivatives-synjournal and properties[J]. Macromolecular Materials and Engineering, 2004,289(1): 63-69. doi: 10.1002/(ISSN)1439-2054
[2]	Prochaska K, Kędziora P, Le Thanh J, et al. Surface activity of commercial food grade modified starches[J]. Colloids and Surfaces B: Biointerfaces, 2007,60(2): 187-194. doi: 10.1016/j.colsurfb.2007.06.005 pmid: 17644351
[3]	Sun Fangyan, Wang Meng, Wang Jianzi, et al. Hygroscopicity, moisture retention and viscosity stability of pullulan polysaccharides[J]. Journal of Tianjin University of Science & Technology, 2016,31(4): 20-24.
[4]	Kanmani P, Lim S T. Development and characterization of novel probiotic-residing pullulan/starch edible films[J]. Food Chemistry, 2013,141(2): 1041-1049. doi: 10.1016/j.foodchem.2013.03.103
[5]	Niu B, Shao P, Chen H, et al. Structural and physiochemical characterization of novel hydrophobic packaging films based on pullulan derivatives for fruits preservation[J]. Carbohydrate Polymers, 2019,208:276-284. doi: 10.1016/j.carbpol.2018.12.070 pmid: 30658801
[6]	Shah N N, Vishwasrao C, Singhal R S, et al. n-Octenyl succinylation of pullulan: Effect on its physico-mechanical and thermal properties and application as an edible coating on fruits[J]. Food Hydrocolloids, 2016,55:179-188. doi: 10.1016/j.foodhyd.2015.11.026
[7]	Zhao Z, Xiong X, Zhou H, et al. Effect of lactoferrin on physicochemical properties and microstructure of pullulan‐based edible films[J]. Journal of the Science of Food and Agriculture, 2019,99(8): 4150-4157. doi: 10.1002/jsfa.9645 pmid: 30767229
[8]	Uchida S, Yamamoto A, Fukui I, et al. Siloxane-containing pullulan and method for the preparation thereof: US5583244 [P]. 1996-12-10.
[9]	Kikuchi H. Oil-based thickening agent, oil-based thickening composition, and cosmetic preparation: US14/889733 [P]. 2016-04-28.
[10]	Masato Izume. Process for producing silylated pullulan and cosmetic preparation: US9125837B2 [P]. 2015-09-08.
[11]	Fujiyama N, Yoda Y, Miyazawa K, et al. Oily cosmetic: US15/329081 [P]. 2017-08-10.
[12]	Cécile Nouvel, Philippe Dubois, Edith Dellacherie, et al. Silylation reaction of dextran: Effect of experimental conditions on silylation yield, regioselectivity, and chemical stability of silylated dextrans[J]. Biomacromolecules, 2003,4(5): 1443-1450. doi: 10.1021/bm034119m pmid: 12959617
[13]	He Tong, Yang Cheng. Preparation and properties of branched silane, polyether alkyl co-modified silicone oil emulsifier[J]. China Surfactant Detergent & Cosmetics, 2019,49(9): 572-578.
[14]	Yan Meiling. Preparation of nano cellulose by anhydrous phosphoric acid and modification by acetylation[D]. Haerbin: Northeast Forestry University, 2015.
[15]	Jiang Chao. Study on fully degraded amphiphilic graft copolymer based on hydroxyethyl cellulose[D]. Wuxi: Jiangnan University, 2008.
[16]	Jia Xue. Preparation and properties of maize starch-based film materials[D]. Wuxi: Jiangnan University, 2018.
[17]	Xing Songmin, Wang Yilu. Synthesis technology and product application of organic silicon [M]. Beijing: Chemical Industry Press, 2000: 818-821.
[18]	Bruneel D, Schacht E, Bruyn A D. Structural analysis of succinoylated and chloroformate activated pullulan: NMR study in DMSO solution[J]. Journal of Carbohydrate Chemistry, 1993,12(6): 769-778. doi: 10.1080/07328309308019006
[19]	He Tong. Synthesis and properties of modified branched silicone emulsifier[D]. Wuxi: Jiangnan University, 2019.
[20]	Jin Qiangwei. Comparative study of natural polymer emulsifiers[D]. Shanghai: Shanghai Jiaotong University, 2017.

原料		质量分数/%
油相	5黏硅油	7.67
	15号白油	7.67
	异十二烷	7.67
	乳化剂	2.00
水相	去离子水	至100.00
	NaCl	1.00
	甘油	6.00

样品（取代度）	PBSA3（0.06）	PBSA6（1.55）	PBSA9（1.91）	PBSA15（2.89）
水	+	–	–	–
DMSO	+	–	–	–
DMF	+	○	○	○
甲苯	○	+	+	+
丙酮	–	+	+	○
四氯化碳	–	+	+	+
乙酸乙酯	–	+	+	+
四氢呋喃	○	+	+	+
吡啶	+	+	+	○
甲醇	○	○	–	–
异丙醇	○	+	+	+
正己烷	–	+	+	+
液体石蜡	–	+	+	+
异十二烷	–	+	+	+
角鲨烷	–	○	+	+
D5	–	○	+	+
5黏硅油	–	○	+	+
GTCC	–	+	+	○
霍霍巴油	–	○	○	–

Preparation and properties of trimethylsilyl pullulan

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