亚油酸钠协同二元表面活性剂体系中金红石的浮选特性及机理

doi:10.3969/j.issn.1001-1803.2020.06.004

Abstract

Abstract:

Flotation performances of rutile in binary systems of sodium linoleate （SL） / sodium oleate （SO） and sodium linoleate （SL） / benzohydroxamic acid sodium salt （BHA） were investigated through pure mineral flotation test. Measurements such as Zeta potential, surface tension, contact angle and UV diffuse reflectance spectroscopy were applied to discuss the interaction mechanism between reagents as well as the reagents onto mineral surface. The results indicated that the adding sequence of reagents had a significant influence on rutile flotation behavior and the synergistic effect index of SL/BHA system was better than that of SL/SO system. The adsorption modes of mixed surfactants on rutile surface could be divided into two major categories: ionic co-adsorption and association adsorption. The intermolecular interaction between the reagents and the adsorption properties of the association complexes were critical for the synergistic effect and the rutile flotation in different systems. The flotation behaviors of rutile at different reagent adding orders were consistent with the variations of bandgap width in SL/BHA system while no distinct corresponding relationship was found in SL/SO system.

Key words: mixed surfactants, surface tension, hydrophobic association, rutile flotation

CLC Number:

TQ423

LIU Ming-bao,WANG Ting,WANG Yu-yu,LIU Hu-gang,LI Zhi. Flotation properties and mechanism of rutile in binary surfactant systems containing sodium linoleate[J].China Surfactant Detergent & Cosmetics, 2020, 50(6): 379-386.

Figures/Tables 10

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References 16

[1]	Wang Liping, Wang Gao, Gao Qi, et al. Distribution and production status of titanium resources in China[J]. Chinese Journal of Rare Metals, 2004,28(1) : 265-267.
[2]	Chen Kezhuan, Liu Xianming, Sun Xiangyuan. Analysis for the supply-demand situation and utilization and development prospect of rutile in Xinyi[J]. Modern Ming, 2013 (4) : 126-127.
[3]	Yue Tiebing, Wei Dezhou, Cao Jincheng, et al. Study on the flotation process of fine rutile ore[J]. IM&P, 2005 (3) : 1-3.
[4]	Gao Likun. Distribution floatation theoretic and theoretical research on refractory fine rutile ore[D]. Kunming: Kunming University of Science and Technology, 2009.
[5]	Zhu Jianguang. Collector and regulator for rutile flotation[J]. Metallic Ore Dressing Abord, 2008 (2) : 3-8.
[6]	Gao Likun, Zhang Zonghua, Wang Yajing. Experimental study on mineral processing of a refractory microfine rutile mine in Shanxi[J]. Ming and Metallurgical Engineering, 2008,28(4) : 42-44.
[7]	Wang Yajing, Zhang Zonghua. Study on flotation collectors for fine rutile[J]. Express Information of Mining Industry, 2008 (1) : 31-33.
[8]	Zhu Jianguang, Zhou Jing. Beneficiation technique for ilmenite, rutile and rare earth [M]. Changsha: Central South University Press, 2009.
[9]	Li Hongqiang, Mu Shunxing, Weng Xiaoqing, et al. Rutile flotation with Pb²+ ions as activator: Adsorption of Pb²+ at rutile/water interface [J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2016,506(5) : 431-437.
[10]	Zhang Kai. The combined use of flotation reagents [M]. Beijing: Metallurgical Industry Press, 1994: 58-61.
[11]	Wang Dianzuo, Hu Yuehua. Solution chemistry of flotation [M]. Changsha: Hunan Science and Technology Press, 1988: 113.
[12]	Tian Z R, Voigt J A, Liu J, et al. Complex and oriented ZnO nanostructures[J]. Nat. Mater., 2003,2:821-826.
[13]	Li Ru, Yu Liangmin, Yan Xuefeng, et al. Morphology-controlled preparation and photocatalytic properties of Cu₂O/ZnO microstructures[J]. Chemical Journal of Chinese Universities, 2017,38(2) : 267-274.
[14]	Zhang Wan, Tang Wanying, He Shiying, et al. Synjournal of ZnO-PMPP ximposites for photocatalytic removal of ammonia nitrogen at low concentration[J]. Acta Scientiae Circumstantiae, 2017,37(2) : 267-274.
[15]	Zhao Xiaohua, Su Shuai, Wu Guangli, et al. Preparation and sunlight photocatalytic performance of flower-like ZnO@carbon sphere core-shell structure[J]. Chinese Journal of Inorgnic Chemistry, 2017,33(2) : 276-284.
[16]	Rosalin B, Pachaiappan R, Paramasivam T. A detailed study on Sn⁴+ doped ZnO for enhanced photocatalytic degradation [J]. Appl. Surf. Sci., 2017,433:887-898. doi: 10.1016/j.apsusc.2017.10.127

亚油酸钠质量分数/%	协同效应指数
	后加入亚油酸钠		亚油酸钠与之预先混合		先加入亚油酸钠
	先加入油酸钠	先加入苯甲羟肟酸钠	与油酸钠混合	与苯甲羟肟酸钠混合	后加入油酸钠	后加入苯甲羟肟酸钠
0	0	0	0	0	0	0
10	0.20	0.87	0.44	0.67	0.41	0.68
20	0.26	0.96	0.39	0.85	0.38	0.83
30	0.35	0.94	0.38	0.94	0.37	0.86
40	0.28	0.85	0.30	0.86	0.29	0.80
50	0.23	0.79	0.24	0.74	0.24	0.73
60	0.17	0.68	0.19	0.64	0.19	0.67
70	0.12	0.59	0.14	0.55	0.14	0.56
80	0.09	0.47	0.10	0.45	0.09	0.45
90	0.05	0.36	0.07	0.37	0.06	0.36
100	0	0	0	0	0	0

药剂制度		拟合曲线	拟合优度	标准偏差	P值
亚油酸钠与之预先混合	与油酸钠混合	ε=81.74+18.28n-7.18n²+1.02n³-0.05n⁴	R²=0.98	2.37	<10^-4
亚油酸钠与之预先混合	与苯甲羟肟酸钠混合	ε=38.10+43.80n-12.33n²+1.50n³-0.07n⁴	R²=0.99	2.26	<10^-4
后添加亚油酸钠	先添加油酸钠	ε=84.30+14.57n-5.92n²-0.86n³-0.04n⁴	R²=0.98	2.11	<10^-4
后添加亚油酸钠	先添加苯甲羟肟酸钠	ε=29.51+54.23n-15.76n²+1.94n³-0.09n⁴	R²=0.99	2.51	<10^-4
先添加亚油酸钠	后添加油酸钠	ε=59.78-5.62n+1.37n²-0.11n³	R²=0.98	1.53	<10^-4
先添加亚油酸钠	后添加苯甲羟肟酸钠	ε=36.12+45.37n-12.59n²+1.49n³-0.07n⁴	R²=0.99	1.96	<10^-4

药剂体系	药剂添加顺序	药剂可能的吸附形式	备注
油酸钠与亚油酸钠混合体系	预先混合后再添加	a互相诱导;b多层缔合吸附	兼具物理吸附和化学吸附
	先添加油酸钠后添加亚油酸钠	a互相诱导;b多层缔合吸附	兼具物理吸附和化学吸附
	先添加亚油酸钠后添加油酸钠	互相诱导	单分子层化学吸附为主
苯甲羟肟酸钠与亚油酸钠混合体系	预先混合后再添加	互相诱导	单分子层化学吸附为主
	先添加油酸钠后添加苯甲羟肟酸钠	互相诱导	单分子层化学吸附为主
	先添加苯甲羟肟酸钠后添加油酸钠	互相诱导	单分子层化学吸附为主

Flotation properties and mechanism of rutile in binary surfactant systems containing sodium linoleate

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