聚甘油脂肪酸酯W/O/W多重乳液的稳定性研究

doi:10.3969/j.issn.1001-1803.2020.05.007

Abstract

Abstract:

The W/O/W multiple emulsion was prepared by using polyglycerol-2-dioleate and decaglycerin monolaurate instead of Span-80 and Tween-80 as W/O and O/W emulsifiers, respectively, and using liquid paraffin as the oil phase. The delamination rate of the emulsion was used as the standard for the stability of the emulsion. The effects of emulsifier type, emulsifier mass fraction and oil-water ratio on the stability of W/O/W multiple emulsion system were discussed. The rheological properties of the emulsion were measured by a rotary rheometer. The effects of fatty alcohols （C_mH₂_m₊₁OH, m=12, 14, 16, 18, 20） and polymers （xanthan gum, hydroxyethyl cellulose, nucleocapsid） on the rheological properties of W/O/W multiple emulsions were investigated. The results show that the suitable W/O/W multiple emulsions has a superior composition. The primary emulsion （W/O）: polyglycerol-2-dioleate has a mass fraction of 10%, and V（liquid paraffin）∶V（water）= 2∶1; W/O/W multiple emulsion: octaglycerol monolaurate mass fraction is 6%, V（primary emulsion）∶ V（water）=9∶10, fatty alcohol （cetyl alcohol） mass fraction is 2%, the high polymer （xanthan gum） mass fraction is 0.15%.

Key words: polyglycerol fatty acid ester, multiple emulsion, rheology, stability

CLC Number:

O648.2+3

HU Ming-jie,XU Hu-jun. Study on the stability of polyglycerol fatty acid ester W/O/W multiple emulsion[J].China Surfactant Detergent & Cosmetics, 2020, 50(5): 319-324.

Figures/Tables 12

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References 19

[1]	Wei Huixian, Zhong Fang, Ma Jianguo . Influences of emulsifying parameters on the stability and drug encapsulation efficiency of W/O/W multiple emulsions[J]. Journal of Chemical Engineering of Chinese Universities, 2008,22(4) : 659-665.
[2]	Liu Wenli, Jiao Weizhou, Liu Youzhi , et al. Progress in study of stability and application of W/O/W multiple emulsion[J]. China Surfactant Detergent ＆ Cosmetics, 2012,42(5) : 366-370.
[3]	Zeng Lanlan, Yang Cheng . Stability of paraffin oil W/O/W multiple emulsions and the ability of vitamin-C encapsulation[J]. Flavour Fragrance Cosmetics, 2009,10(5) : 23-25.
[4]	Clitor J F Souza, Talita A Comunian, Márcia G C Kasemodel , et al. Microencapsulation of lactase by W/O/W emulsion followed by complex coacervation: Effects of enzyme source, addition of potassium and core to shell ratio on encapsulation efficiency, stability and kinetics of release[J]. Food Research International, 2019,121:754-764.
[5]	Li Fangfang, Jia Hongjiao, Tian Yonghong , et al. Progress in research work with respect to multiple emulsions[J]. China Surfactant Detergent ＆ Cosmetics, 2014,44(4) : 222-225.
[6]	Nie Linghong . Synjournal and application of polyglycerol fatty acid ester[J]. Food and Fat, 2003,23(1) : 45-46.
[7]	Yang Kunyu, Jiang Wenwei, Chu Yuyu . Study on the surface properties of the polyglycerol fatty acid esters[J]. Detergent ＆ Cosmetics, 2010,33(5) : 25-28.
[8]	Medeiros E S, Offeman R D, Klamczynski A P , et al. Synjournal, characterization and nanocomposite formation of poly (glycerol succinate-co-maleate) with nanocrystalline cellulose[J]. Journal of Polymers and the Environment, 2014,22(2) : 219-226.
[9]	Qiao Guohua . Study on synthesis and application of polyglycerol fatty acid ester[D]. Wuxi: Jiangnan University, 2009.
[10]	Geng Erhuan . Synthesis and properties of high polyglycerol fatty acid esters[D]. Taiyuan: China Daily Chemical Industry Research Institute, 2014.
[11]	Charlemagne D, Legoy M D . Enzymatic synjournal of polyglycerol-fatty acid esters in a solvent-free system[J]. Journal of the American Oil Chemists’ Society, 1995,72(1) : 61-65.
[12]	He Yanyan . Study on synthesis and application property of polyglycerol fatty acid ester as ecological textile auxiliary agent[D]. Shanghai: Donghua University, 2008.
[13]	Wang Yaohuan . Preparation and stability of simferin multiple emulsion[D]. Chongqing: Chongqing University, 2014.
[14]	Yuan Yuan, Mao Like, Gao Yanxiang . Effects of tween series emulsifiers on particle size and stability of β-carotene nanoemulsions[J]. Food Science, 2008,29(5) : 181-186.
[15]	Liu Huajie, Liu Song . Stability of white oil W/O/W multiple emulsions[J]. China Surfactant Detergent ＆ Cosmetics, 2007,37(2) : 88-91.
[16]	Liu Hongjing . The stability of W/O/W multiple emulsion and its application in loading insulin[D]. Dalian: Dalian University of Technology, 2006.
[17]	Luo Shaoqiang, Zhang Chen, Hu Liuyun , et al. Stability and rheology of three types of W/O/W multiple emulsions emulsified with lecithin[J]. Journal of Dispersion Science and Technology, 2016,38(11) : 1530-1535. doi: 10.1080/01932691.2016.1259074
[18]	Lobato-Calleros C, Rodriguez E, Sandoval-Castilla O , et al. Reduced-fat white fresh cheese-like products obtained from W₁/O/W₂ multiple emulsions: Viscoelastic and high-resolution image analyses[J]. Food Research International, 2006,39(6) : 678-685.
[19]	Liu Huanhuan . Interfacial behavior of cyclodextrins at oil-water interface and properties of their stabilized emulsions[D]. Wuxi: Jiangnan University, 2009.

W/O型乳化剂	黏度/（Pa·s）	W/O乳液分层率/%
Span-80 聚甘油-2-二油酸酯	6.859 0 8.037 7	11 2
甘油单异硬脂肪酸酯	5.534 2	18
甘油单油酸酯	4.874 6	25

O/W型乳化剂	黏度/（Pa·s）	W/O/W多重乳液分层率/%
Tween-80 十聚甘油单辛酸酯	12.353 0 10.325 1	5 12
十聚甘油单癸酸酯	11.936 4	7
十聚甘油单月桂酸酯	14.214 2	1

Study on the stability of polyglycerol fatty acid ester W/O/W multiple emulsion

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