氧化型染黑用途染发剂中32种染料监测结果分析

doi:10.3969/j.issn.1001-1803.2020.01.010

Abstract

Abstract:

The 25 batches of commercially available oxidized blackening hair dyes were collected, and the contents of 32 selected chemical substances including p-Phenylenediamine in these products were assessed according to Safety and Technical Standards for Cosmetics （2015 edition）. The content analysis results were compared with the approved formulas and labels of each product. The purpose of the survey was to gather information about the production and quality of this kind of hair dyes on domestic market, with the goal of uncovering the safety risks and providing supervision suggestions. The result shows that none of the eight prohibited components involved in the 32 components are detected in all investigated products. With regard to the 24 permitted hair dye components, phenyl methyl pyrazolone was found to exceed the permitted limit in 6 batches of the products. 17 batches of samples were inconsistent with the test results and the approved formulas, 16 batches of samples were inconsistent with the test results and the labels, and 5 batches of samples were inconsistent with the approved formulas and the labels. 17 batches of samples in total were problematic, with the problem discovery rate of 68%. According to the results, it is necessary to strengthen the inspection of hair dyes containing phenyl methyl pyrazolone, and carry out the special rectification in packages and labels. The reasons for the excessive addition of phenyl methyl pyrazolone was analyzed in the survey.

Key words: oxidized blackening hair dyes, approved formulas, labels, phenyl methyl pyrazolone, supervision suggestions

CLC Number:

TQ658.3

LI Bin,ZHANG Wei-qing,LIU Hui-jin,HOU Li-nan,QIAO Ya-sen,WANG Hai-yan. Analysis on the determination results of 32 kinds of dyes used in oxidized blackening hair dyes[J].China Surfactant Detergent & Cosmetics, 2020, 50(1): 54-58.

Figures/Tables 3

Tab. 1

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References 20

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准用组分	检出批次	使用频率/%	含量区间/%	限量（氧化型）	超限量添加批次
对苯二胺	22	88	0.8~1.8	≤2.0%	0
对氨基苯酚	0	0	0	≤0.5%	0
甲苯-2,5-二胺硫酸盐	3	12	0.8~0.9	≤4.0%（以游离基计）	0
间氨基苯酚	17	68	0.003~0.2	≤1.0%	0
2-氯对苯二胺硫酸盐	0	0	0	≤0.5%	0
间苯二酚	25	100	0.02~0.48	≤1.25%	0
4-氨基-2-羟基甲苯	1	4	0.03	≤1.5%	0
2-甲基间苯二酚	0	0	0	≤1.0%	0
6-氨基间甲酚	0	0	0	≤1.2%	0
苯基甲基吡唑啉酮	14	56	0.04~0.81	≤0.25%	6
4-氨基-3-硝基苯酚	0	0	0	≤1.5%	0
2,4-二氨基苯氧基乙醇盐酸盐	6	24	0.1~0.2	≤2.0%	0
4-氨基间甲酚	1	4	0.02	≤1.5%	0
2-氨基-3-羟基吡啶	0	0	0	≤0.3%	0
N,N-双（2-羟乙基）对苯二胺硫酸盐	2	8	0.02~0.2	≤2.5%（以硫酸盐计）	0
对甲基氨基苯酚硫酸盐	0	0	0	≤0.68%	0
4-硝基邻苯二胺	0	0	0	≤0.5%	0
2,6-二氨基吡啶	0	0	0	≤0.15%	0
6-羟基吲哚	0	0	0	≤0.5%	0
4-氯间苯二酚	2	8	0.1	≤0.5%	0
2,7-萘二酚	0	0	0	≤0.5%	0
N-苯基对苯二胺	0	0	0	≤3.0%	0
1,5-萘二酚	0	0	0	≤0.5%	0
1-萘酚	0	0	0	≤1.0%	0

准用组分	使用数量/批				使用频率/%			不一致率/%
准用组分	检测结果	批件配方	标签标示	检测结果	批件配方	标签标示	检测结果与批件配方	检测结果与标签标示	批件配方与标签标示
对苯二胺	22	19	19	88	76	76	0	12	12
甲苯-2,5-二胺硫酸盐	3	4	4	12	16	16	4	4	0
间氨基苯酚	17	13	16	68	52	64	24	16	12
间苯二酚	25	18	23	100	72	92	16	8	20
4-氨基-2-羟基甲苯	1	1	1	4	4	4	0	0	0
2-甲基间苯二酚	0	1	1	0	4	4	4	4	0
苯基甲基吡唑啉酮	14	2	4	56	8	16	52	40	4
2,4-二氨基苯氧基乙醇盐酸盐	6	13	11	24	52	44	44	44	16
4-氨基间甲酚	1	1	1	4	4	4	0	0	0
N,N-双（2-羟乙基）对苯二胺硫酸盐	2	1	3	8	4	12	12	4	8
4-氯间苯二酚	2	2	2	8	8	8	0	0	0
1-萘酚	0	0	1	0	0	4	0	4	0
							68 （17/25）	64 （16/25）	20 （5/25）

准用染发剂	《规范》	欧盟法规（EU）
对氨基苯酚	氧化型染发产品：≤0.5%; 非氧化型染发产品：不得检出	氧化型染发产品：≤0.9%; 非氧化型染发产品：不得检出
间氨基苯酚	氧化型染发产品：≤1.0%; 非氧化型染发产品：不得检出	氧化型染发产品：≤1.2%; 非氧化型染发产品：不得检出
2-甲基间苯二酚	氧化型染发产品：≤1.0%; 非氧化型染发产品：≤1.8%	氧化型染发产品：≤1.8%; 非氧化型染发产品：≤1.8%
4-氯间苯二酚	氧化型染发产品：≤0.5%; 非氧化型染发产品：不得检出	氧化型染发产品：≤2.5%; 非氧化型染发产品：不得检出

Analysis on the determination results of 32 kinds of dyes used in oxidized blackening hair dyes

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