基于N-[4-（三乙基铵甲撑）苯酰基]己内酰胺氯化物的活化氧漂体系在纺织品室温洁白洗涤中的应用

doi:10.3969/j.issn.1001-1803.2019.04.004

Abstract

Abstract:

N-[4-（triethylammoniomethyl） benzoyl] caprolactam chloride （TBCC） was used for activation of sodium perborate, sodium percarbonate and percarbamide for room-temperature cleaning of white fabrics contaminated with tea, coffee and wine. The experiment results show that the activated perborate and percarbonate systems exhibit outstanding room-temperature cleaning performance, but the activated percarbamide system exhibits poor room-temperature cleaning performance. It is found that the incorporation of sodium carbonate in the TBCC-activated percarbamide system can effectively improve its room-temperature cleaning performance. The TBCC-activated peroxide systems added with anionic and nonionic surfactants have no apparent change in their cleaning performance.

Key words: cleaning, peroxide, bleach activator, activated peroxide system, fabric

CLC Number:

TQ649

SHAO Dong-yan,CHAI Wen-long,DU Jin-mei,WANG Hong-bo,XU Chang-hai. Performance of activated peroxide system based on N-[4-（triethylammoniomethyl） benzoyl] caprolactam chloride in room-temperature cleaning of colored contaminants on textiles[J].China Surfactant Detergent & Cosmetics, 2019, 49(4): 224-228.

Figures/Tables 7

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Fig.1

Tab.5

Fig.2

References 10

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纺织品	颜色						WI
纺织品	L*	a*	b*	C*	h*	ΔE	WI
原样	94.67	-0.13	4.24	4.24	91.73		67.55
茶渍	88.35	1.79	7.15	7.37	75.93	7.22	38.50
咖啡渍	80.26	3.57	16.79	17.17	78.01	19.46	非白
红酒渍	74.60	10.24	3.38	10.79	18.28	22.61	非白

洗涤配方	WI
洗涤配方	茶渍纺织品	咖啡渍纺织品	红酒渍纺织品
1	46.19	非白	41.36
2	54.79	非白	41.98
3	52.15	34.30	40.43
4	71.43	57.53	65.33
5	43.94	31.69	41.34
6	68.12	56.17	59.09
7	49.86	26.98	28.60
8	54.63	27.26	40.77
9	50.75	非白	39.54
10	50.48	30.07	40.53
11	71.75	55.61	64.55
12	47.98	28.39	38.99
13	68.76	54.15	59.04
14	52.58	24.48	27.63
15	51.92	25.03	42.25

洗涤配方	洗涤前pH			洗涤后pH
洗涤配方	茶渍纺织品	咖啡渍纺织品	红酒渍纺织品	茶渍纺织品	咖啡渍纺织品	红酒渍纺织品
4	8.71	8.84	8.61	7.82	7.99	7.56
6	8.22	8.34	7.91	7.23	7.54	7.32
8	4.39	4.44	4.16	4.40	4.44	4.21
11	8.74	8.72	8.62	7.69	7.84	7.47
13	8.18	8.19	7.76	6.82	7.45	7.04
15	4.15	4.30	4.00	4.15	4.36	3.96

Na₂CO₃/（g·L^-1）	pH		WI
Na₂CO₃/（g·L^-1）	洗涤前	洗涤后	WI
0	4.00	3.96	42.25
0.80	7.68	6.99	57.89
1.00	8.20	7.28	63.94
1.25	8.50	7.40	64.12
1.50	8.71	7.67	65.18
1.75	8.77	8.00	66.38
2.00	9.05	8.38	67.12

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Performance of activated peroxide system based on N-[4-（triethylammoniomethyl） benzoyl] caprolactam chloride in room-temperature cleaning of colored contaminants on textiles

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洗涤配方	ρ/（g·L^-1）
洗涤配方	SDBS	Triton X-100	EDTA	过硼酸钠	过碳酸钠	过氧化脲	TBCC
1	0	0	0	0	0	0	0
2	1.0	0	0	0	0	0	0
3	1.0	0	1.0	1.50	0	0	0
4	1.0	0	1.0	1.50	0	0	5.51
5	1.0	0	1.0	0	1.57	0	0
6	1.0	0	1.0	0	1.57	0	5.51
7	1.0	0	1.0	0	0	1.41	0
8	1.0	0	1.0	0	0	1.41	5.51
9	0	1.0	0	0	0	0	0
10	0	1.0	1.0	1.50	0	0	0
11	0	1.0	1.0	1.50	0	0	5.51
12	0	1.0	1.0	0	1.57	0	0
13	0	1.0	1.0	0	1.57	0	5.51
14	0	1.0	1.0	0	0	1.41	0
15	0	1.0	1.0	0	0	1.41	5.51