连结基对甜菜碱型双子表面活性剂表面活性和泡沫性能的影响

doi:10.13218/j.cnki.csdc.2018.10.003

Abstract

Abstract: A series of betaine-type Gemini surfactants (C_s-BGS where C is the methylene of the spacer,s=2,4,6) were synthesized from sodium 3-chloro-2-hydroxypropanesulfonate,oleamidopropyl dimethylamine and bromoalkane.The chemical structures of the prepared compounds were characterized by FT-IR and ¹H NMR.Their critical micelle concentration (cmc)in the aqueous solution at 25 ℃ was determined by Wilhelmy and electrical conductivity methods.The results show that with the increasing length of the spacer,the values of cmc and equilibrium surface tension (γ_cmc)areincreased.C₂-BGS has exhibited the lowest cmc,nice efficiency in reducing surface tension (pc₂₀),strong adsorption at the air-water interface,and relatively good foaming performance.In addition,the adsorption and micellization behaviors of C_s-BGS were estimated by pc₂₀,minimum surface area per molecule (A_min),standard adsorption free energy (ΔG⁰_ads)and standard micellization free energy (ΔG⁰_mic).The results show that these properties of C_s-BGS are significantly influenced by the length of the spacer,and the ability to promote adsorption is stronger than to promote micellization.

Key words: Gemini surfactant, betaine, spacer group, surface activity, foaming properties

CLC Number:

TQ423

LAI Xiao-juan,LIU Pei,TIAN Wei,WANG Jie,HUI Yan-ni,JIA You-liang. Effects of the spacer on the surface activity and foaming properties of betaine Gemini surfactants[J].China Surfactant Detergent & Cosmetics, 2018, 48(10): 558-563.

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Effects of the spacer on the surface activity and foaming properties of betaine Gemini surfactants

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