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China Surfactant Detergent & Cosmetics ›› 2017, Vol. 47 ›› Issue (9): 492-496.doi: 10.13218/j.cnki.csdc.2017.09.003

• Development and application • Previous Articles     Next Articles

Study on the surface performance of cardanol polyoxyethylene ether

ZHAO Xue-hua1,2, HUANG Zhong-rui2, KANG Wen-qian2, WANG Li-min1,2, CHE Fei3, ZHAI Zhao-kai3   

  1. 1.Shanghai Key Laboratory of Functional Materials Chemistry,Shanghai 200237,China;
    2.Institute of Fine Chemicals,School of Chemistry and Molecular Engineering,East China University of Science and Technology,Shanghai 200237,China;
    3.Shanghai Bronkow Chemical Co.,Ltd.,Shanghai 201512,China
  • Received:2017-05-23 Published:2019-03-20

Abstract: Surface activity of cardanol polyoxyethylene ether BGF-10 and the effects of different additives on the surface activity were studied.Results show that the critical micelle concentration (cmc) of BGF-10 is 6.09×10-6 mol/L,and the lowest surface tension (γcmc) is 38.08 mN/m at 25 ℃.Moreover,BGF-10 displays a better resistance to hard water and a strong salt tolerance to monovalent inorganic salts.With the increase of concentration of divalent inorganic salt,the surface activity of BGF-10 is enhanced.Monohydric alcohol can reduce the surface tension of BGF-10.The ability of BGF-10 to form micelles increases in the beginning and then decreases with the increase of monohydric alcohol concentration.BGF-10 displays a synergistic effect with other surfactants,especially with hexadecyltrimethylammonium bromide (CTAB),and its cmc synergizes upto 2.52%,while the γcmc synergizes upto 11.49%.BGF-10 displays a good emulsifying power for paraffin oil,as well as both thickening and defoaming performance.

Key words: cardanol polyoxyethylene ether, critical micelle concentration, surface tension, blending

CLC Number: 

  • TQ423.2