胺基CO2开关型表面活性剂的合成与性能研究

doi:10.13218/j.cnki.csdc.2017.07.003

Abstract

Abstract: Surfactant tetradecyldiethylenetriamine (C₁₄DETA) was synthesized with 1-bromotetradecane and diethylenetriamine as starting materials.Its structure was characterized by FT-IR and ¹H NMR spectrum.Measurement of reversibility of conductivity,reversibility of pH values,and the opening action of synergistic effect with SDS demonstrate the good CO₂ switchability of C₁₄DETA.The critical micelle concentrations (cmc) of tetradecyldiethylenetriamine bicarbonate (C₁₄DETA-CO₂) and the mixed system of SDS/C₁₄DETA-CO₂ are 1.0×10^-2 and 1.0×10^-4 mol/L respectively.Results of emulsifying performance of C₁₄DETA-CO₂ for n-decane/water system prove the good emulsifying power of C₁₄DETA-CO₂.The emulsion is water-in-oil type,and its better emulsifying conditions are:mass fraction of C₁₄DETA-CO₂,4%;and the volume ratio of oil/water,1∶1 or 1∶2.

Key words: CO₂ switchable surfactant, characterization, critical micelle concentration, performance

CLC Number:

TQ423

ZHANG Peng, MEI Ping, LAI Lu. Synthesis and performance of CO₂ switchable amine surfactants[J].China Surfactant Detergent & Cosmetics, 2017, 47(7): 369-373.

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Synthesis and performance of CO₂ switchable amine surfactants

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Synthesis and performance of CO2 switchable amine surfactants

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Synthesis and performance of CO₂ switchable amine surfactants