湿法球磨改性蒙脱土及其稳定液体石蜡/水Pickering乳液的制备

doi:10.13218/j.cnki.csdc.2016.12.005

Abstract

Abstract: Wet ball mill method was applied to prepare modified montmorillonite (DDA-MMT) by the intercalation of didodecyldimethylammonium bromide (DDAB) with Na-montmorillonite (Na-MMT) as the basic material.Then the resultant DDA-MMT was applied to emulsify liquid paraffin to form O/W Pickering emulsions under the action of ultrasound.The resultant DDA-MMT was characterized by XRD,TEM,FT-IR,contact angle measurement,Zeta potential and laser particle size analyzer.The effects of DDA-MMT mass concentration,pH of aqueous phase and ionic strength on the stability of the Pickering emulsions were also investigated.Experimental results showed that DDAB has successfully intercalated into the interlayer of Na-MMT under the mechanical action of the ball mill,causing the size,Zeta potential and three phase contact angle change from 910.7 nm,-26.8 mV and 121.7° to 603.8 nm,38.3 mV and 86.9° respectively.In comparison with Na-MMT particles,DDA-MMT particles are more easily to aggregate between the oil-water interfaces and displays better emulsification stability.With the increasing of DDA-MMT mass concentration,the particle size of the Pickering emulsions decreases,the volume fraction of the emulsion increases and the stability of the emulsion becomes better.When the pH of aqueous phase is in the range of 6.26～8.36,and the NaCl concentration is 20 mmol/L,the stability of the Pickering emulsion prepared by DDA-MMT is in the best condition.

Key words: Na-montmorillonite, didodecyldimethylammonium bromide, Pickering emulsion, stability

CLC Number:

O648.2+3

YAN Hui-qiong,CHEN Xiu-qiong,SONG Huang-wang,LI Jia-cheng,WANG Xiang-hui,LIN Qiang. Preparation of liquid paraffin/water Pickering emulsions stabilized by modified montmorillonite with wet ball mill method[J].China Surfactant Detergent & Cosmetics, 2016, 46(12): 697-702.

References

[1] SALCEDO I,AGUZZI C,SANDRI G,et al.In vitro biocompatibility and mucoadhesion of montmorillonite chitosan nanocomposite:a new drug delivery [J] .Appl Clay Sci,2012,55:131-137.
[2] LI N,MA J Z,BAO Y.Development on modification of montmorillonite [J] .Chem Res,2009,20(1):98-103.
[3] CORNEJO L,CELIS R,DOMINGUEZ C,et al.Use of modified montmorillonites to reduce herbicide leaching in sports turf surfaces:laboratory and field experiments [J] .Appl Clay Sci,2008,42:284-291.
[4] BHATTACHARYYA K G,GUPTA S S.Adsorption of a few heavy metals on natural and modified kaolinite and montmorillonite:a review [J] .Adv Colloid Interf Sci,2008,140:114-131.
[5] YU D,LIN Z,LI Y.Octadecenylsuccinic anhydride pickering emulsion stabilized by γ-methacryloxy propyl trimethoxysilane grafted montmorillonite [J] .Colloid Surface A,2013,422:100-109.
[6] DESTRIBATS M,ROUVET M,GEHIN-DELVAL C,et al.Emulsions stabilised by whey protein microgel particles:towards food-grade Pickering emulsions [J] .Soft Matter,2014,10(36):6941-6954.
[7] 谭伟强,臧渡洋,李云飞,等.SiO₂纳米颗粒与聚氧乙烯对Pickering 乳液的协同稳定作用[J] .高等学校化学学报,2014,35(1):85-91.
[8] KALASHNIKOVA I,BIZOT H,CATHALA B,et al.New Pickering emulsionsstabilized by bacterial cellulose nanocrystals [J] .Langmuir,2011,27(12):7471-7479.
[9] 陈秀琼,颜慧琼,李嘉诚,等.Ugi反应海藻酸衍生物协同疏水改性高岭土稳定Pickering乳液的制备[J] .日用化学工业,2015,45(4):185-190.
[10] 聂聪,赵臻璐,王小群.球磨改性处理对MMT及PET/MMT复合材料的影响[J] .塑料,2011,40(2):5-8.
[11] 林红娇,晏泓,王亓杰,等.硅烷偶联剂对金属氢氧化物粉体的机械球磨改性[J] .中国粉体技术,2011,17(4):36-40.
[12] TORRES L G,ITURBE R,SNOWDEN M J,et al.Preparation of O/W emulsions stabilized by solid particles and their characterization by oscillatory rheology [J] .Colloid Surface A,2007,302:439-448.
[13] JOSHI G V,KEVADIYA B D,PATEL H A,et al.Montmorillonite as a drug delivery system:intercalation and in vitro release of timolol maleate [J] .Int J Pharm,2009,374:53-57.
[14] ZHANG W Y,LU L B,CHENG Y,et al.Clean and rapid synthesis of double metal cyanide complexes using mechanochemistry [J] .Green Chem,2011,13:2701-2703.
[15] 王珂,朱湛,郭炳南,等.有机蒙脱土的制备及其结构表征[J] .北京理工大学学报,2002,22(2):240-243.
[16] SINGH B,SHARMA D K,GUPTA A.Controlled release of the fungicide thiram from starch-alginate-clay based formulation [J] .Appl Clay Sci,2009,45:76-82.
[17] YAN H,CHEN X,FENG Y,et al.Modification of montmorillonite by ball-milling method for immobilization and delivery of acetamiprid based on alginate/exfoliated montmorillonite nanocomposite [J] .Polym Bull,2016,73:1185-1206.
[18] GAO M,ZHU P X.A starch/milled-montmorillonite nanocomposite for warp sizing [J] .Starch-Starke,2012,64:97-104.
[19] 颜慧琼,陈秀琼,李嘉诚,等.基于Ugi多组分反应的海藻酸酰胺衍生物改性二氧化硅纳米粒子的制备[J] .高等学校化学学报,2016,37(5):1018-1024.
[20] BINKS B P,CLINT J H.Solid wettability from surface energy components:relevance to Pickering emulsions [J] .Langmuir,2002,18:1270-1273.
[21] ELEK N,HOFFMAN R,RAVIV U,et al.Novaluron nanoparticles:formation and potential use in controlling agricultural insect pests [J] .Colloid Surface A,2010,372:66-72.
[22] WEN C,YUAN Q,LIANG H,et al.Preparation and stabilization of d-limonene Pickering emulsions by cellulose nanocrystals [J] .Carbohyd Polym,2014,112:695-700.
[23] YI C,YANG Y,ZHU Y,et al.Self-assembly and emulsification of poly{[styrene-alt-maleic acid] -co-[styrene-alt-(N-3,4-dihydroxyphenylethyl-maleamic acid)] } [J] .Langmuir,2012,28(25):9211-9222.
[24] WHITBY C P,FORNASIERO D,RALSTON J.Effect of adding anionic surfactant on the stability of Pickering emulsions [J] .J Colloid Interf Sci,2009,329(1):173-181.

Preparation of liquid paraffin/water Pickering emulsions stabilized by modified montmorillonite with wet ball mill method

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