响应面法优化咪唑啉硫酸酯盐的合成及性能研究

doi:10.13218/j.cnki.csdc.2016.06.003

Abstract

Abstract: Under the catalysis of urea,a kind of imidazoline sulfate salt was synthesized with amino sulfonic acid as the sulfating reagent,lauric acid and N-hydroxyethyl-ethylenediamine as starting materials.The chemical structure of the target product was characterized by IR and ¹H NMR.Based upon results obtained from single factor experiments and in combination with response surface method,the optimal synthesis conditions were determined as:n(imidazoline)∶n(amino sulfonic acid)=1∶1.09;reaction temperature,107 ℃;reaction time,3.7 h;dosage of the catalyst,2.93% of the total mass of the reactants.Under the above-mentioned conditions,the reaction yield achieves 75.20%.Surface activity and foaming performance of the product were measured.The results showed that imidazoline sulfate salt displays good surface activity and foaming performance.

Key words: imidazoline sulfate salt, surface activity, response surface method

CLC Number:

TQ423.3

GUO Rui,CHENG Min,YANG Jiang-yue,LI Huan-le,LIU Ai-yu. Optimization of synthesis of imidazoline sulfate salt by response surface method and study of its performance[J].China Surfactant Detergent & Cosmetics, 2016, 46(6): 314-319.

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Optimization of synthesis of imidazoline sulfate salt by response surface method and study of its performance

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