不对称型磺基琥珀酸双酯盐双子表面活性剂的合成与性能

doi:10.13218/j.cnki.csdc.2015.12.005

Abstract

Abstract: Lauryl alcohol,maleic anhydride and lauric acid monoethanolamide were used as starting materials to synthesized asymmetric Gemini sulfosuccinate surfactant.The optimized conditions for diesterification are as following:reaction temperature,140 ℃;reaction time,6 h;and n(lauryl alcohol maleic acid monoester)∶n(lauric acid monoethanolamide)=1∶1.The structure of the target compound was characterized by FTIR and ¹HNMR.The surface tension,foaming performance and emulsifying power of the product were measured.Results showed that the product has low cmc as 2.21×10^-5 mol/L and γ_cmc as 31.1 mN/m.It displays stronger foaming power and better foam stability.Water separation time of the emulsion made of the product achieves 278 s.

Key words: Gemini surfactant, succinic acid diester, asymmetry

CLC Number:

TQ423

WANG Hong-di, MA Jian-zhong, LÜ Bin, GAO Jian-jing, XUE Dan. Synthesis and performance of asymmetric Gemini sulfosuccinate surfactant[J].China Surfactant Detergent & Cosmetics, 2015, 45(12): 685-689.

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Synthesis and performance of asymmetric Gemini sulfosuccinate surfactant

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