脂肪酸皂体系的相行为及其稳定性研究

doi:10.13218/j.cnki.csdc.2015.12.001

Abstract

Abstract: Phase behavior and stability of soap base systems made of single fatty acid as well as blends of two and three kinds of fatty acid separately were studied.The influence of addition of glycerin on phase behavior and stability of the soap base systems were also discussed.Results showed that the phase behavior of soap base systems formed by two or three kinds of fatty acid (lauric,myristic,palmitic and stearic) may change that of soap base system of single fatty acid.Meanwhile,the addition of glycerin may also enlarge the region of micelle phase of the soap base system of the blended fatty acids,and part of micelle and crystal two phases changes into micelle and laminar two phases.

Key words: fatty acid soap, phase behavior, glycerin, stability

CLC Number:

TQ648

LI Fang-fang, CHEN Ming-hua, ZHANG Wan-ping. Phase behavior and stability of fatty acid soap systems[J].China Surfactant Detergent & Cosmetics, 2015, 45(12): 661-669.

References

[1] MCBAIN J W,MALCOLMC C.Phase rule equilibria of acid soaps.I.Anhydrous acid potassium laurate[J].The Journal of Physical Chemistry,1932,37(6):675-684.
[2] BENTON D P,HOWE P G,PUDDINGTON I E.The mesomorphic behavior of anhydrous soaps.Part I.Light transmission by alkali metal stearates[J].Canadian Journal of Chemistry,1955,33(9):1384-1391.
[3] BENTON D P,HOWE P G,FAKNANA R,et al.The mesomrphic behavior of anhydrous soaps.Part II.Densities of alkali metal stearates[J].Canadian Journal of Chemistry,1955,33(12):1798-1805.
[4] HONIG J G,SINGLERRY C R.The physical-chemical behavior of oil-dispersible soap solutions.III.Collid structure in dilute arylstea-rate-benzene system[J].The Journal of Physical Chemistry,1956,60(8):1114-1119.
[5] HERRICK A B,ERIC J.Manufacture of soap from fatty acids[J].The Journal of the American Oil Chemists’ Society,1963,40:615-618.
[6] EKWALL P,MNADELL L.Solutions of alkali soaps and water in fatty acids I.Region of existence of the solutions[J].Kolloid-Zeitschrift und Zeitschrift fir Polymere,1968,233:938-944.
[7] FONTELL K,MANDELL L.Phase equilibria and phase structure in the ternary systems sodium or potassium octanoate-octanoic acid-water[J].Colloid and Polymer Science,1993,271(10):974-991.
[8] LAWRENCE A S C,BINGHAM A,CAPPER C B,et al.The penetration of water and aqueous soap solutions into fatty substances containing one or two polar groups[J].The Journal of Physical Chemistry,1964,68(12):3470-3476.
[9] MEHROTRA K N,MAMTA J.Effect of chain length on acoustic behaviour of chromium soap solutions in xylene and methanol mixture
[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,1995,95:229-234.
[10] 王红霞,张高勇.脂肪醇聚氧乙烯醚(15)/水体系相行为及流变性研究[J].日用化学工业,2001,31(2):1-4.
[11] 刘高令,杜志平,王国永.LAS/AEO-9/肥皂/水拟三元体系的相行为和流变性能[J].日用化学工业,2010,40(1):1-5.
[12] 于涛,杨柳,曹绪龙,等.磺基甜菜碱型两性离子表面活性剂的相行为研究[J].化学工业与工程技术,2013,34(5):61-65.
[13] 鲁娟. 相图法研究聚集体的形成及作药物载体的研究[D].济南:山东师范大学,2012.
[14] ZHU S,HEPPENSTALL M,BUTLER M F,et al.Acid soap and phase behavior of stearic acid and triethanolamine stearate[J].The Journal of Physical Chemistry B,2005,109(23):11753-11761.
[15] 岳会. 表面活性剂复配体系的相行为与结构特性研究[D].扬州:扬州大学,2007.
[16] MATTHEW L,PAN Y,LAUGHLIN R G.Spectroscopic and thermal characterization of 1∶2 sodium soap/fatty acid acid-soap crystals[J].The Journal of Physical Chemistry,1996,100(1):357-361.
[17] LIN B,MCORMICK A V,REINHARD S.Solubility of sodium soaps in aqueous salt solutions[J].Journal of Colloid and Interface Science,2005,291:543-549.
[18] MARIANA P B,KRASSIMIR D,KRALCHEVSKY P A,et al.Coexistence of micelles and crystallites in solutions of potassium myristate:soft matter vs.solid matter[J].Colloids and Surfaces A:Physico-chemical and Engineering Aspects,2010,354:172-187.
[19] 汤晓露. 低毒性两亲分子体系的相行为及其应用研究[D].济南:山东师范大学,2012.
[20] 郭春伟. 表面活性剂相关系统的构效关系及应用[D].杭州:浙江大学,2011.
[21] 李军. 表面活性剂离子液体在水溶液中的聚集行为[D].济南:山东大学,2012.
[22] 王丹. 烷基咪唑Gemini型表面活性剂的合成及相行为的研究[D].济南:山东大学,2013.
[23] LIN B,MCORMICK A V,REINHARD S.Solubility of sodium soaps in aqueous salt solutions[J].Journal of Colloid and Interface Science,2005,291:543-549.
[24] 王华. 含表面活性剂复配体系自组装机理的理论研究[D].济南:山东大学,2014.
[25] RENUGAMBAAL N R.Performance and microstructural study on soap using different fatty acids and cations[J].Journal of Surfactant Detergent,2011,14:463-471.
[26] TZOCHEVA S S,KRALCHEVSKY P A,DANOV K D,et al.Solubility limits and phase diagrams for fatty acids in anionic (SLES) and zwitterionic (CAPB) micellar surfactant solutions[J].Journal of Colloid and Interface Science,2012,369:274-286.
[27] AHMAD N,MUHAMMAD R,TAJUDDIN H A,et al.Effect of glycolipids on the stability and electrophoretic mobility ofdecanoic acid vesicles[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2014,443:96-101.

Phase behavior and stability of fatty acid soap systems

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