二烯丙基甲基烷基溴化铵的合成及性能研究

doi:10.13218/j.cnki.csdc.2015.08.004

Abstract

Abstract: Four kinds of diallylmethylalkyl (n=4,6,8,10) quaternary ammonium salt (refers to as C₄,C₆,C₈ and C₁₀) were synthesized by using diallylmethylamine (DAM) and 1-bromo alkane with separate chain length as raw materials.The chemical structure of the products was characterized by IR,¹HNMR and elemental analysis.Meanwhile,their surface activity,water solubility and flocculation property were examined.Results showed that the recommended better process conditions are:acetone as the solvent;molar ratio of DAM to 1-bromo alkane,1∶1.1;reaction time,64~72 h at 50~60 ℃.The product yields achieve 86.16%,78.02%,75.46% and 68.10% respectively.With the increase of the alkyl chain length,their critical micelle concentration decreases as 3.2×10^-2,2.1×10^-2,1.7×10^-2 and 9.0×10^-3 mol/L respectively;as well as their corresponding surface tension decreases as 40.3,38.5,34.3 and 33.1 mN/m respectively.All of them show good water solubility,and their Krafft points are all less than 0 ℃.Their flocculation capacity to kaolin and diatomite are in the order of C₁₀>C₈>C₆>C₄.

Key words: quaternary ammonium salt, diallylmethylalkylammonium bromide, synthesis, properties

CLC Number:

TQ423.12

TAO Xian-ping, ZHANG Yue-jun, XIA Sheng-li. Synthesis and properties of diallylmethylalkylammonium bromide[J].China Surfactant Detergent & Cosmetics, 2015, 45(8): 434-438.

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Synthesis and properties of diallylmethylalkylammonium bromide

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