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China Surfactant Detergent & Cosmetics ›› 2014, Vol. 44 ›› Issue (2): 79-82.doi: 10.13218/j.cnki.csdc.2014.02.018

• Development and application • Previous Articles     Next Articles

Synthesis and properties of dodecylamine sodium chloroacetate as water-based printing ink additive

YANG Lu1, JIANG Ping-ping1, ZHANG Ping-bo1, GAO Xue-wen2, QIAO Qian-qian1   

  1. 1.School of Chemical and Material Engineering,Jiangnan University,Wuxi,Jiangsu 214122,China;
    2.Jiangsu Caihua Packaging Group Company,Kunshan,Jiangsu 215300,China
  • Received:2013-09-11 Published:2019-04-09

Abstract: Dodecylamine sodium chloroacetate (DSC) was synthesized from dodecylamine and dichloroacetic acid as starting materials.The first step product is dodecylamine chloroacetic acid (DCA).Optimum reaction conditions for preparing DCA were determined as:mole ratio of dichloroacetic acid to dodecylamine 1∶1.5;mass fraction of the catalyst 1%;reaction time 18 h at 120 ℃.The DCA yield achieves 58.91%.Structure of the final product DSC was characterized by IR.The measurement results for surface activities of the final product showed that critical micelle concentration (cmc) of DSC achieves 3.38×10-3 mol·L-1 and lowest surface tension (γcmc) of DSC achieves 27.43 mN·m-1.The dispersing property of DSC was identified by UV-vis and ZetaPALS,and the optimum mass fraction of DSC as dispersant in water-based printing ink is 1.6%.

Key words: dodecylamine sodium chloroacetate, synthesis, water-based printing ink, dispersant

CLC Number: 

  • TQ423.11